NULL

Base Information

• Chemical Name: NULL
• CAS No.: 102540-15-8
• Molecular Formula: C10H9BrO2
• Molecular Weight: 241.084
• Hs Code.: 2916399090
• Mol file: 102540-15-8.mol

Synonyms:methyl 2-bromocinnamate;methyl trans-3-(2-bromophenyl)propenoate;3-(2-bromophenyl)propenoic acid methyl ester;(E)-methyl 3-(2-bromophenyl)propenoate;3-(2-bromophenyl)acrylic acid methyl ester;

Chemical Property of NULL

Chemical Property:

• PSA: 26.30000
• LogP: 2.63530

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of NULL

There total 33 articles about NULL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-Bromo-2-iodobenzene (583-55-1) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → 3-(2-bromophenyl)-acrylic acid methyl ester (102540-15-8)

Guidance literature:

With triethylamine; In N,N-dimethyl-formamide; toluene; at 100 ℃; for 20h;

DOI:10.1016/j.tetlet.2013.05.128

Reference yield: 99.0%

1-Bromo-2-iodobenzene (583-55-1) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → methyl (2E)-3-(2-bromophenyl)-2-propenoate (102540-15-8,123100-53-8,92991-89-4)

Guidance literature:

With triethylamine; In water; N,N-dimethyl-formamide; toluene; at 100 ℃; for 20h;

DOI:10.1039/c0ob00523a

Reference yield: 98.0%

methyl (triphenylphosphoranylidene)acetate (21204-67-1,2605-67-6) + ortho-bromobenzaldehyde (6630-33-7) → methyl (2E)-3-(2-bromophenyl)-2-propenoate (102540-15-8,123100-53-8,92991-89-4)

Guidance literature:

In tetrahydrofuran; at 25 ℃; for 18h;

DOI:10.1021/jm00113a030

upstream raw materials:

2-bromocinnamic acid

methyl (triphenylphosphoranylidene)acetate

ortho-bromobenzaldehyde

1-Bromo-2-iodobenzene

Downstream raw materials:

methyl 2-(3-oxo-1,3-dihydroisobenzofuran-1-yl)acetate

(E)-3-(2-bromophenyl)-2-propen-1-ol

trans-2-bromocinnamaldehyde

(E)-tert-butyl 2-(3-(2-bromophenyl)allylamino)ethylcarbamate