3,3′-diiodo-6,6′-dimethylbiphenyl

Base Information

• Chemical Name: 3,3′-diiodo-6,6′-dimethylbiphenyl
• CAS No.: 1392203-19-8
• Molecular Formula: C₁₄H₁₂I₂
• Molecular Weight: 434.058
• Mol file: 1392203-19-8.mol

Synonyms:

Chemical Property of 3,3′-diiodo-6,6′-dimethylbiphenyl

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,3′-diiodo-6,6′-dimethylbiphenyl

There total 1 articles about 3,3′-diiodo-6,6′-dimethylbiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

2,2'-dimethyl-1,1'-biphenyl (605-39-0) → 3,3′-diiodo-6,6′-dimethylbiphenyl (1392203-19-8)

Guidance literature:

With sulfuric acid; iodine; iodic acid; acetic acid; In tetrachloromethane; water; at 80 ℃; for 18h;

DOI:10.1016/j.orgel.2011.08.012

Reference yield: 48.0%

3,3′-diiodo-6,6′-dimethylbiphenyl (1392203-19-8) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 3-(carbazol-9-yl)-6,6-dimethyl-3′-iodobiphenyl

Guidance literature:

With potassium phosphate; copper(l) iodide; trans-1,2-Diaminocyclohexane; In 1,4-dioxane; for 20h; Inert atmosphere; Reflux;

DOI:10.1021/cm4023216

Reference yield:

3,3′-diiodo-6,6′-dimethylbiphenyl (1392203-19-8) → 3-(carbazol-9-yl)-6,6′-dimethyl-3′-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan)biphenyl

Guidance literature:

Multi-step reaction with 2 steps

1: copper(l) iodide; potassium phosphate; trans-1,2-Diaminocyclohexane / 1,4-dioxane / 20 h / Inert atmosphere; Reflux

2: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / dimethyl sulfoxide / 3 h / 80 °C / Inert atmosphere

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium phosphate; copper(l) iodide; trans-1,2-Diaminocyclohexane; potassium acetate; In 1,4-dioxane; dimethyl sulfoxide; 1: |Goldberg Reaction / 2: |Miyaura Borylation Reaction;

DOI:10.1021/cm4023216

upstream raw materials:

2,2'-dimethyl-1,1'-biphenyl