Ethyl 5-(4-chlorophenyl)penta-2,4-dienoate

Base Information

Chemical Name:Ethyl 5-(4-chlorophenyl)penta-2,4-dienoate
CAS No.:49678-20-8
Molecular Formula:C₁₃H₁₃ClO₂
Molecular Weight:236.698
Hs Code.:
DSSTox Substance ID:DTXSID90710823

Synonyms:ethyl 5-(4-chlorophenyl)penta-2,4-dienoate;39806-17-2;DTXSID90710823

Suppliers and Price of Ethyl 5-(4-chlorophenyl)penta-2,4-dienoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ethyl 5-(4-chlorophenyl)penta-2,4-dienoate

Chemical Property:

XLogP3:3.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:5
Exact Mass:236.0604073
Heavy Atom Count:16
Complexity:263

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCOC(=O)C=CC=CC1=CC=C(C=C1)Cl

Technology Process of Ethyl 5-(4-chlorophenyl)penta-2,4-dienoate

There total 4 articles about Ethyl 5-(4-chlorophenyl)penta-2,4-dienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 24583-70-8
3-(4-chlorophenyl)-2-propene-1-ol

: 49678-20-8
(2E,4E)-5-(4-Chloro-phenyl)-penta-2,4-dienoic acid ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: manganese(IV) oxide / dichloromethane / 20 °C

2: toluene / 110 °C

With manganese(IV) oxide; In dichloromethane; toluene; 2: |Wittig Olefination;
DOI:10.1039/c7ob00562h

Reference yield:

: 104-88-1
4-chlorobenzaldehyde

: 49678-20-8
(2E,4E)-5-(4-Chloro-phenyl)-penta-2,4-dienoic acid ethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: toluene / 110 °C

2: diisobutylaluminium hydride / dichloromethane; hexane / 1 h / -60 - 0 °C / Inert atmosphere

3: manganese(IV) oxide / dichloromethane / 20 °C

4: toluene / 110 °C

With manganese(IV) oxide; diisobutylaluminium hydride; In hexane; dichloromethane; toluene; 1: |Wittig Olefination / 4: |Wittig Olefination;
DOI:10.1039/c7ob00562h

Reference yield:

: 6048-06-2
ethyl-p-chlorocinnamate

: 49678-20-8
(2E,4E)-5-(4-Chloro-phenyl)-penta-2,4-dienoic acid ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: diisobutylaluminium hydride / dichloromethane; hexane / 1 h / -60 - 0 °C / Inert atmosphere

2: manganese(IV) oxide / dichloromethane / 20 °C

3: toluene / 110 °C

With manganese(IV) oxide; diisobutylaluminium hydride; In hexane; dichloromethane; toluene; 3: |Wittig Olefination;
DOI:10.1039/c7ob00562h