1-(2-Methoxy-5-methylphenyl)-camphenilon

Base Information

• Chemical Name: 1-(2-Methoxy-5-methylphenyl)-camphenilon
• CAS No.: 33171-57-2
• Molecular Formula: C₁₇H₂₂O₂
• Molecular Weight: 258.36
• Mol file: 33171-57-2.mol

Synonyms:

Chemical Property of 1-(2-Methoxy-5-methylphenyl)-camphenilon

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(2-Methoxy-5-methylphenyl)-camphenilon

There total 1 articles about 1-(2-Methoxy-5-methylphenyl)-camphenilon which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(2-Methoxy-5-methylphenyl)-camphen (33059-65-3) → 1-(2-Methoxy-5-methylphenyl)-camphenilon (33171-57-2)

Guidance literature:

Multistep reaction; (i) O₃, MeOH, CH₂Cl₂, (ii) P(OMe)3;

DOI:10.1016/S0040-4020(01)98013-5

Reference yield:

1-(2-Methoxy-5-methylphenyl)-camphenilon (33171-57-2) → (1S,2S,4R)-1-(2-Methoxy-5-methyl-cyclohexa-2,4-dienyl)-3,3-dimethyl-bicyclo[2.2.1]heptan-2-ol

Guidance literature:

Multi-step reaction with 2 steps

1: Li, liq. NH₃ / propan-2-ol; diethyl ether

2: Rh(PPh₃)3Cl

With ammonia; lithium; Wilkinson's catalyst; In diethyl ether; isopropyl alcohol;

DOI:10.1016/S0040-4020(01)98013-5

Reference yield:

1-(2-Methoxy-5-methylphenyl)-camphenilon (33171-57-2) → (1S,2S,4R)-1-(2-Methoxy-5-methyl-cyclohexa-1,4-dienyl)-3,3-dimethyl-bicyclo[2.2.1]heptan-2-ol (33171-58-3)

Guidance literature:

With ammonia; lithium; In diethyl ether; isopropyl alcohol;

DOI:10.1016/S0040-4020(01)98013-5

upstream raw materials:

1-(2-Methoxy-5-methylphenyl)-camphen

Downstream raw materials:

(1S,2S,4R)-1-(2-Methoxy-5-methyl-cyclohexa-1,4-dienyl)-3,3-dimethyl-bicyclo[2.2.1]heptan-2-ol