Technology Process of C28H43NO4Si
There total 3 articles about C28H43NO4Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
camphor-10-sulfonic acid;
In
methanol; dichloromethane;
at 0 ℃;
for 6h;
DOI:10.1002/chem.201201332
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: copper(l) iodide; methyllithium / tetrahydrofuran; diethyl ether / 8 h / 0 °C / Inert atmosphere
1.2: 0.5 h / 0 °C / Inert atmosphere
2.1: lithium triethylborohydride / tetrahydrofuran / 0.5 h / 0 - 25 °C / Inert atmosphere
3.1: [bis(acetoxy)iodo]benzene; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / dichloromethane / 0.5 h / 0 °C
4.1: dichloromethane / 12 h / 25 °C / Inert atmosphere
5.1: copper(l) iodide; methyllithium / tetrahydrofuran; diethyl ether / 8 h / 0 °C / Inert atmosphere
5.2: 0 °C / Inert atmosphere
6.1: camphor-10-sulfonic acid / methanol; dichloromethane / 6 h / 0 °C
With
copper(l) iodide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; camphor-10-sulfonic acid; methyllithium; lithium triethylborohydride;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane;
DOI:10.1002/chem.201201332
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: lithium triethylborohydride / tetrahydrofuran / 0.5 h / 0 - 25 °C / Inert atmosphere
2.1: [bis(acetoxy)iodo]benzene; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / dichloromethane / 0.5 h / 0 °C
3.1: dichloromethane / 12 h / 25 °C / Inert atmosphere
4.1: copper(l) iodide; methyllithium / tetrahydrofuran; diethyl ether / 8 h / 0 °C / Inert atmosphere
4.2: 0 °C / Inert atmosphere
5.1: camphor-10-sulfonic acid / methanol; dichloromethane / 6 h / 0 °C
With
copper(l) iodide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; camphor-10-sulfonic acid; methyllithium; lithium triethylborohydride;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane;
DOI:10.1002/chem.201201332