[10,10-2H2]-1-bromoundecane

Base Information

• Chemical Name: [10,10-2H2]-1-bromoundecane
• CAS No.: 386223-64-9
• Molecular Formula: C₁₁H₂₃Br
• Molecular Weight: 237.192
• Mol file: 386223-64-9.mol

Synonyms:

Chemical Property of [10,10-2H2]-1-bromoundecane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [10,10-2H2]-1-bromoundecane

There total 8 articles about [10,10-2H2]-1-bromoundecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

[10,10-2H2]-1-undecanol (386223-62-7) → [10,10-2H2]-1-bromoundecane (386223-64-9)

Guidance literature:

With N-Bromosuccinimide; In N,N-dimethyl-formamide; at 50 ℃; for 0.25h;

DOI:10.1021/jo010560w

Reference yield:

8-bromooctanol (50816-19-8) → [10,10-2H2]-1-bromoundecane (386223-64-9)

Guidance literature:

Multi-step reaction with 8 steps

1: 97 percent / LiBr; p-toluenesulfonic acid / 16 h / 20 °C

2: 60 percent / Na / ethanol / 26 h / Heating

3: 60 percent / Na / ethanol; ethane-1,2-diol / 0.5 h / 85 - 90 °C

4: 95 percent / NaBD₄ / methanol / 1 h / 20 °C

5: 73 percent / trimethylamine hydrochloride; triethylamine / CH₂Cl₂ / 1.5 h / 0 °C

6: LiAlD₄ / diethyl ether / 3 h / 20 °C

7: 108 mg / HCl / methanol / 16 h / 20 °C

8: 70 percent / N-bromosuccinimide / dimethylformamide / 0.25 h / 50 °C

With hydrogenchloride; N-Bromosuccinimide; lithium aluminium deuteride; sodium borodeuteride; sodium; trimethylamine hydrochloride; toluene-4-sulfonic acid; triethylamine; lithium bromide; In methanol; diethyl ether; ethanol; dichloromethane; ethylene glycol; N,N-dimethyl-formamide;

DOI:10.1021/jo010560w

Reference yield:

1-bromo-8-methoxymethoxy-octane (194926-03-9) → [10,10-2H2]-1-bromoundecane (386223-64-9)

Guidance literature:

Multi-step reaction with 7 steps

1: 60 percent / Na / ethanol / 26 h / Heating

2: 60 percent / Na / ethanol; ethane-1,2-diol / 0.5 h / 85 - 90 °C

3: 95 percent / NaBD₄ / methanol / 1 h / 20 °C

4: 73 percent / trimethylamine hydrochloride; triethylamine / CH₂Cl₂ / 1.5 h / 0 °C

5: LiAlD₄ / diethyl ether / 3 h / 20 °C

6: 108 mg / HCl / methanol / 16 h / 20 °C

7: 70 percent / N-bromosuccinimide / dimethylformamide / 0.25 h / 50 °C

With hydrogenchloride; N-Bromosuccinimide; lithium aluminium deuteride; sodium borodeuteride; sodium; trimethylamine hydrochloride; triethylamine; In methanol; diethyl ether; ethanol; dichloromethane; ethylene glycol; N,N-dimethyl-formamide;

DOI:10.1021/jo010560w

upstream raw materials:

[10,10-2H₂]-1-undecanol

8-bromooctanol

1-bromo-8-methoxymethoxy-octane

11-(methoxymethoxy)undecan-2-one