[Fe(C₁₂H₈N₂)(C₆H₂(CH₃)3)2]

Base Information

• Chemical Name: [Fe(C₁₂H₈N₂)(C₆H₂(CH₃)3)2]
• CAS No.: 86006-01-1
• Molecular Formula: C₃₀H₃₀FeN₂
• Molecular Weight: 474.429
• Mol file: 86006-01-1.mol

Synonyms:

Chemical Property of [Fe(C₁₂H₈N₂)(C₆H₂(CH₃)3)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe(C₁₂H₈N₂)(C₆H₂(CH₃)3)2]

There total 2 articles about [Fe(C₁₂H₈N₂)(C₆H₂(CH₃)3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

1,10-Phenanthroline (66-71-7) + iron(dichloride)*1.5(tetrahydrofuran) + 2-mesitylmagnesium bromide (2633-66-1) → [Fe(C12H8N2)(C6H2(CH3)3)2] (86006-01-1)

Guidance literature:

In tetrahydrofuran; 1,4-dioxane; byproducts: MgBrCl*dioxane; to a suspn. of FeCl2*1.5THF in THF and dioxane a soln. of MesMgBr in THF is dropwise added at -30°C, mixt. is allowed to warm to room temp. with stirring (3 h); soln. is filtered, the filtrate is evapd. to dryness, residue is dissolved in Et2O, soln. is filtered, to the filtrate 1,10-phenanthroline is added, mixt. is kept for 6 h, ppt. is collected by filtn., washed with Et2O and dried in vac., elem. anal.;

Reference yield:

1,10-Phenanthroline (66-71-7) + bis(mesityl) iron(II) (59774-47-9) → [Fe(C12H8N2)(C6H2(CH3)3)2] (86006-01-1)

Guidance literature:

In diethyl ether; inert gas; addn. of org. compd. in ether to soln. of Fe-compd. in ether;

Reference yield: 98.0%

[Fe(C12H8N2)(C6H2(CH3)3)2] (86006-01-1) + L-phenylalanine (63-91-2,25191-15-5,658-69-5,67675-33-6) → bis(L-phenylalaninato)(1,10-phenanthroline)iron

Guidance literature:

In tetrahydrofuran; to a soln. of Fe(Mes)2(phen) L-phenylalanine is added, mixt. is kept for 72 h (N2); ppt. is collected by filtn., washed with Et2O and dried in vac., ppt. is recrystd. by slow extraction into refluxing THF, elem. anal.;

upstream raw materials:

1,10-Phenanthroline

2-mesitylmagnesium bromide

bis(mesityl) iron(II)

Downstream raw materials:

bis(DL-phenylalaninato)(1,10-phenanthroline)iron