SeWSe(CuP(C₆H₅)3Se)2Cu(P(C₆H₅)3)Cl

Base Information

• Chemical Name: SeWSe(CuP(C₆H₅)3Se)2Cu(P(C₆H₅)3)Cl
• CAS No.: 143618-53-5
• Molecular Formula: C₅₄H₄₅ClCu₃P₃Se₄W
• Molecular Weight: 1512.65
• Mol file: 143618-53-5.mol

Synonyms:

Chemical Property of SeWSe(CuP(C₆H₅)3Se)2Cu(P(C₆H₅)3)Cl

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of SeWSe(CuP(C₆H₅)3Se)2Cu(P(C₆H₅)3)Cl

There total 3 articles about SeWSe(CuP(C₆H₅)3Se)2Cu(P(C₆H₅)3)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.6%

chlorobis(triphenylphosphine)copper(I) + [tetrabutylammonium]2[WSe4] → SeWSe(CuP(C6H5)3Se)2Cu(P(C6H5)3)Cl (143618-53-5)

Guidance literature:

In neat (no solvent, solid phase); well-ground mixt. of Cu complex and tungsten deriv. heated at 80° for 6 h under N2; resulting black solid extd. with CH2Cl2, filtered; filtrate diffused with Et2O; after 2 d, red crystals sepd. off; identified by elem. anal., nonlinear optical studies and single crystalX-ray diffraction;

DOI:10.1016/S0022-2860(99)00414-7

Reference yield: 40.0%

2(C3H7)4N(1+)*WSe4(2-) = {(C3H7)4N}2{WSe4} + 4(P(C6H5)3)*2Cu(1+)*2(BH3)*2(CN)(1-)={(P(C6H5)3)2CuBH3(CN)}2 → SeWSe(CuP(C6H5)3Se)2Cu(P(C6H5)3)Cl (143618-53-5)

Guidance literature:

With NH₄Cl; In dichloromethane; under N2; stirred for 30 min;; filtered; layered with THF; crystd.; elem. anal.;;

Reference yield:

(Cu(P(C6H5)3))(1+) (81218-61-3) + 2(C3H7)4N(1+)*WSe4(2-) = {(C3H7)4N}2{WSe4} → SeWSe(CuP(C6H5)3Se)2Cu(P(C6H5)3)Cl (143618-53-5)

Guidance literature:

With NH₄Cl; In N,N-dimethyl-formamide;

upstream raw materials:

(Cu(P(C₆H₅)3))⁽¹⁺⁾