[2,5-(phenyl-κC(2''),phenyl)]-1,3,4-oxadiazole-(κN1)(tetracarbonylmanganese(I))

Base Information

• Chemical Name: [2,5-(phenyl-κC(2''),phenyl)]-1,3,4-oxadiazole-(κN1)(tetracarbonylmanganese(I))
• CAS No.: 930297-46-4
• Molecular Formula: C₁₈H₉MnN₂O₅
• Molecular Weight: 388.218
• Mol file: 930297-46-4.mol

Synonyms:

Chemical Property of [2,5-(phenyl-κC(2''),phenyl)]-1,3,4-oxadiazole-(κN1)(tetracarbonylmanganese(I))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2,5-(phenyl-κC(2''),phenyl)]-1,3,4-oxadiazole-(κN1)(tetracarbonylmanganese(I))

There total 1 articles about [2,5-(phenyl-κC(2''),phenyl)]-1,3,4-oxadiazole-(κN1)(tetracarbonylmanganese(I)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

benzylpentacarbonylmanganese + 2,5-bis-(phenyl)-1,3,4-oxadiazole (725-12-2) → [2,5-(phenyl-κC(2''),phenyl)]-1,3,4-oxadiazole-(κN1)(tetracarbonylmanganese(I)) (930297-46-4) + [2,5-(diphenyl-κC(2'),κC(2''))]-1,3,4-oxadiazole-(κN1,κN2)bis(tetracarbonylmanganese(I)) (930297-47-5)

Guidance literature:

In n-heptane; (Ar); soln. of ligand and Mn complex in heptane was refluxed for 12 h; Mn complex was added; refluxed for 24 h; cooled to room temp.; solvent removed (vac.); chromd. (silica gel, 5°C, hexane/CH2Cl2, 9/1 to 8/2); elem. anal.;

DOI:10.1016/j.jorganchem.2006.11.007

Reference yield: 82.0%

[2,5-(phenyl-κC(2''),phenyl)]-1,3,4-oxadiazole-(κN1)(tetracarbonylmanganese(I)) (930297-46-4) + diazodiphenylmethane (908093-98-1) → [1''2''2':η-2'-(diphenylmethylene)-phenyl]-5-phenyl-1,3,4-oxadiazole-(κN)-tricarbonylmanganese(I) (930297-48-6)

Guidance literature:

In n-heptane; toluene; (Ar); soln. of Mn complex in heptane/toluene (1/1) was refluxed; soln. of diazomethane in toluene was added dropwise over 25 min; heated for 35 min; cooled to room temp.; evapd. (vac.); chromd. (silica gel, 6°C, hexane/CH2Cl2, 6/4); volatiles evapd.; elem. anal.;

DOI:10.1016/j.jorganchem.2006.11.007

upstream raw materials:

2,5-bis-(phenyl)-1,3,4-oxadiazole

Downstream raw materials:

[1''2''2':η-2'-(diphenylmethylene)-phenyl]-5-phenyl-1,3,4-oxadiazole-(κN)-tricarbonylmanganese(I)