Cu(OEP)-TPC-ester

Base Information

• Chemical Name: Cu(OEP)-TPC-ester
• CAS No.: 929039-46-3
• Molecular Formula: C₅₉H₆₄CuN₅O₃
• Molecular Weight: 954.735
• Mol file: 929039-46-3.mol

Synonyms:

Chemical Property of Cu(OEP)-TPC-ester

Chemical Property:

Purity/Quality:

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• Pictogram(s):  
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Technology Process of Cu(OEP)-TPC-ester

There total 1 articles about Cu(OEP)-TPC-ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

[4'-iodo-1,1'-biphenyl]-4-yl-1-oxyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrole-3-carboxylate (1030611-41-6) + copper(II)-meso-ethynyl-octaethylporphyrin (1031231-11-4) → Cu(OEP)-TPC-ester (929039-46-3)

Guidance literature:

With PdCl₂(PPh₃)2; CuI; PPh₃; In tetrahydrofuran; triethylamine; under Ar, Schlenk techniques; CuI (0.09 mmol) added to soln. of ester (0.12 mmol) + PdCl2(PPh3)2 (0.018 mmol) in NEt3+THF; mixt. of Cu complex (0.12 mmol) and PPh3 (0.05 mmol) in NEt3+THF added; stirred (room temp., 16 h, dark) and (50°C, 1.5 h); cooled to room temp.; solvent removed (vac.); solid dissolved in CH2Cl2;washed with H2O; dried over Na2SO4; CH2Cl2 removed (vac.); residue diss olved in CH2Cl2/hexane (2:1); column chromy. (Al2O3, 4% H2O, CH2Cl2/hexane 2:1); recrystd.; elem. anal.;

DOI:10.1021/jp710504k

upstream raw materials:

[4'-iodo-1,1'-biphenyl]-4-yl-1-oxyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrole-3-carboxylate

copper(II)-meso-ethynyl-octaethylporphyrin