E-(2S,3R,4S,5R)-5-(2-methoxystyryl)-2-methyltetrahydrofuran-3,4-diol

Base Information

Chemical Name:E-(2S,3R,4S,5R)-5-(2-methoxystyryl)-2-methyltetrahydrofuran-3,4-diol
CAS No.:1393602-02-2
Molecular Formula:C₁₄H₁₈O₄
Molecular Weight:250.295
Hs Code.:

Synonyms:

Suppliers and Price of E-(2S,3R,4S,5R)-5-(2-methoxystyryl)-2-methyltetrahydrofuran-3,4-diol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of E-(2S,3R,4S,5R)-5-(2-methoxystyryl)-2-methyltetrahydrofuran-3,4-diol

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of E-(2S,3R,4S,5R)-5-(2-methoxystyryl)-2-methyltetrahydrofuran-3,4-diol

There total 8 articles about E-(2S,3R,4S,5R)-5-(2-methoxystyryl)-2-methyltetrahydrofuran-3,4-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₇H₂₂O₄

: 1393602-02-2
E-(2S,3R,4S,5R)-5-(2-methoxystyryl)-2-methyltetrahydrofuran-3,4-diol

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; water; at 20 ℃;
DOI:10.3998/ark.5550190.0013.633

Reference yield:

: 1260097-00-4
1,4-anhydro-5-deoxy-2,3-O-isopropylidene-1-methyl-5-(1-phenyl-1H-tetrazol-5-ylsulfanyl)-D-galacto-pentitol

: 1393602-02-2
E-(2S,3R,4S,5R)-5-(2-methoxystyryl)-2-methyltetrahydrofuran-3,4-diol

Guidance literature:: Multi-step reaction with 3 steps

1: ammonium molybdate; dihydrogen peroxide / tetrahydrofuran; ethanol / 24 h / 20 °C

2: potassium hexamethylsilazane / 1,2-dimethoxyethane; toluene / 10 h / -30 - 20 °C / Inert atmosphere

3: hydrogenchloride / tetrahydrofuran; water / 20 °C

With hydrogenchloride; ammonium molybdate; dihydrogen peroxide; potassium hexamethylsilazane; In tetrahydrofuran; 1,2-dimethoxyethane; ethanol; water; toluene; 2: Barbier reaction;
DOI:10.3998/ark.5550190.0013.633

Reference yield:

: 30725-00-9
2,3-O-isopropylidene-D-ribonic-γ-lactone

: 1393602-02-2
E-(2S,3R,4S,5R)-5-(2-methoxystyryl)-2-methyltetrahydrofuran-3,4-diol

Guidance literature:: Multi-step reaction with 9 steps

1: dmap; triethylamine / N,N-dimethyl-formamide / 8 h / 20 °C

2: diisobutylaluminium hydride / hexane; toluene / 4 h / -78 - -50 °C / Inert atmosphere

3: dmap / dichloromethane / 12 h / 0 - 20 °C

4: hexane; dichloromethane / 144 h / -30 - -18 °C

5: tetrabutyl ammonium fluoride / tetrahydrofuran / 12 h / 20 °C

6: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 1 h / 0 °C

7: ammonium molybdate; dihydrogen peroxide / tetrahydrofuran; ethanol / 24 h / 20 °C

8: potassium hexamethylsilazane / 1,2-dimethoxyethane; toluene / 10 h / -30 - 20 °C / Inert atmosphere

9: hydrogenchloride / tetrahydrofuran; water / 20 °C

With hydrogenchloride; dmap; ammonium molybdate; di-isopropyl azodicarboxylate; tetrabutyl ammonium fluoride; dihydrogen peroxide; potassium hexamethylsilazane; diisobutylaluminium hydride; triethylamine; triphenylphosphine; In tetrahydrofuran; 1,2-dimethoxyethane; ethanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; toluene; 6: Mitsunobu reaction / 8: Barbier reaction;
DOI:10.3998/ark.5550190.0013.633