Dimethyl-dithiocarbamic acid (S)-1-((3aR,7aR)-1,3-dimethyl-2-oxo-octahydro-2λ⁵-benzo[1,3,2]diazaphosphol-2-yl)-4-(3-phenoxy-phenyl)-butyl ester

Base Information

• Chemical Name: Dimethyl-dithiocarbamic acid (S)-1-((3aR,7aR)-1,3-dimethyl-2-oxo-octahydro-2λ⁵-benzo[1,3,2]diazaphosphol-2-yl)-4-(3-phenoxy-phenyl)-butyl ester
• CAS No.: 157238-96-5
• Molecular Formula: C₂₇H₃₈N₃O₂PS₂
• Molecular Weight: 531.723

Synonyms:

Chemical Property of Dimethyl-dithiocarbamic acid (S)-1-((3aR,7aR)-1,3-dimethyl-2-oxo-octahydro-2λ⁵-benzo[1,3,2]diazaphosphol-2-yl)-4-(3-phenoxy-phenyl)-butyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of Dimethyl-dithiocarbamic acid (S)-1-((3aR,7aR)-1,3-dimethyl-2-oxo-octahydro-2λ⁵-benzo[1,3,2]diazaphosphol-2-yl)-4-(3-phenoxy-phenyl)-butyl ester

There total 3 articles about Dimethyl-dithiocarbamic acid (S)-1-((3aR,7aR)-1,3-dimethyl-2-oxo-octahydro-2λ⁵-benzo[1,3,2]diazaphosphol-2-yl)-4-(3-phenoxy-phenyl)-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(R,R)-N,N'-dimethyl-1,2-diaminocyclohexane (68737-65-5) → Dimethyl-dithiocarbamic acid (S)-1-((3aR,7aR)-1,3-dimethyl-2-oxo-octahydro-2λ5-benzo[1,3,2]diazaphosphol-2-yl)-4-(3-phenoxy-phenyl)-butyl ester (157238-96-5,178153-39-4)

Guidance literature:

Multi-step reaction with 3 steps

1: 81 percent / Et₃N / toluene

2: 1.) n-BuLi / 1.) THF, -78 deg C, 2.) THF, from -78 deg C to RT

3: 1.) n-BuLi / 1.) THF, -78 deg C, 2.) THF, -90 deg C to -70 deg C

With n-butyllithium; triethylamine; In toluene;

DOI:10.1021/ja962505o

Reference yield:

(3aR,7aR)-1,2,3-Trimethyl-octahydro-benzo[1,3,2]diazaphosphole 2-oxide (146983-71-3) → Dimethyl-dithiocarbamic acid (S)-1-((3aR,7aR)-1,3-dimethyl-2-oxo-octahydro-2λ5-benzo[1,3,2]diazaphosphol-2-yl)-4-(3-phenoxy-phenyl)-butyl ester (157238-96-5,178153-39-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) n-BuLi / 1.) THF, -78 deg C, 2.) THF, from -78 deg C to RT

2: 1.) n-BuLi / 1.) THF, -78 deg C, 2.) THF, -90 deg C to -70 deg C

With n-butyllithium;

DOI:10.1021/ja962505o

Reference yield:

Thiram (137-26-8,93196-73-7) + (3aR,7aR)-1,3-Dimethyl-2-[4-(3-phenoxy-phenyl)-butyl]-octahydro-benzo[1,3,2]diazaphosphole 2-oxide (157126-93-7) → Dimethyl-dithiocarbamic acid (S)-1-((3aR,7aR)-1,3-dimethyl-2-oxo-octahydro-2λ5-benzo[1,3,2]diazaphosphol-2-yl)-4-(3-phenoxy-phenyl)-butyl ester (157238-96-5,178153-39-4) + Dimethyl-dithiocarbamic acid (R)-1-((3aR,7aR)-1,3-dimethyl-2-oxo-octahydro-2λ5-benzo[1,3,2]diazaphosphol-2-yl)-4-(3-phenoxy-phenyl)-butyl ester (157126-17-5)

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, -78 deg C, 2.) THF, -90 deg C to -70 deg C;

DOI:10.1021/ja962505o

upstream raw materials:

Thiram

(3aR,7aR)-1,3-Dimethyl-2-[4-(3-phenoxy-phenyl)-butyl]-octahydro-benzo[1,3,2]diazaphosphole 2-oxide

(R,R)-N,N'-dimethyl-1,2-diaminocyclohexane

(3aR,7aR)-1,2,3-Trimethyl-octahydro-benzo[1,3,2]diazaphosphole 2-oxide

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