3-((3S,4R)-4-Benzyloxy-3-methyl-octyl)-2,2-dimethyl-oxirane

Base Information

Chemical Name:3-((3S,4R)-4-Benzyloxy-3-methyl-octyl)-2,2-dimethyl-oxirane
CAS No.:1025943-78-5
Molecular Formula:C₂₀H₃₂O₂
Molecular Weight:304.473
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-((3S,4R)-4-Benzyloxy-3-methyl-octyl)-2,2-dimethyl-oxirane

Chemical Property:

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Technology Process of 3-((3S,4R)-4-Benzyloxy-3-methyl-octyl)-2,2-dimethyl-oxirane

There total 6 articles about 3-((3S,4R)-4-Benzyloxy-3-methyl-octyl)-2,2-dimethyl-oxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 106-25-2
Nerol

: 1025943-78-5
3-((3S,4R)-4-Benzyloxy-3-methyl-octyl)-2,2-dimethyl-oxirane

Guidance literature:: Multi-step reaction with 6 steps

1: 92 percent / tert-butyl hydroperoxide, D-(-)-diethyl tartrate / Ti3)2>4 / CH₂Cl₂ / 3 h / -20 °C

2: 67 percent / NaBH₃CN, BF₃*OEt₂ / tetrahydrofuran

3: 50percent aq. NaOH, benzyltriethylammonium chloride / CH₂Cl₂ / 2 h

4: 1.) Mg, 2.) CuBr*DMS / 1.) THF, 2.) 0 deg C, 3 h

5: 76 percent / NaH / tetrahydrofuran / 1.) room temp., 1 h, 2.) room temp., 10 h; reflux, 90 min

6: 50percent 3-chloroperbenzoic acid / CH₂Cl₂ / 0.33 h / Ambient temperature

With tert.-butylhydroperoxide; sodium hydroxide; copper(I) bromide dimethylsulfide complex; diethyl (2S,3S)-tartrate; boron trifluoride diethyl etherate; N-benzyl-N,N,N-triethylammonium chloride; sodium hydride; sodium cyanoborohydride; magnesium; 3-chloro-benzenecarboperoxoic acid; titanium(IV) isopropylate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00093a037

Reference yield:

: 156633-84-0
(5R,6S)-5-(Benzyloxy)-6,10-dimethyl-9-undecene

: 1025943-78-5
3-((3S,4R)-4-Benzyloxy-3-methyl-octyl)-2,2-dimethyl-oxirane

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 0.333333h; Ambient temperature;
DOI:10.1021/jo00093a037

Reference yield:

: 50727-94-1,62777-72-4,62960-04-7,71030-55-2,76985-26-7,82188-73-6,112456-40-3,112456-65-2,62777-71-3
(2R,3R)-3-methyl-3-(4-methyl-3-pentenyl)oxiranemethanol

: 1025943-78-5
3-((3S,4R)-4-Benzyloxy-3-methyl-octyl)-2,2-dimethyl-oxirane

Guidance literature:: Multi-step reaction with 5 steps

1: 67 percent / NaBH₃CN, BF₃*OEt₂ / tetrahydrofuran

2: 50percent aq. NaOH, benzyltriethylammonium chloride / CH₂Cl₂ / 2 h

3: 1.) Mg, 2.) CuBr*DMS / 1.) THF, 2.) 0 deg C, 3 h

4: 76 percent / NaH / tetrahydrofuran / 1.) room temp., 1 h, 2.) room temp., 10 h; reflux, 90 min

5: 50percent 3-chloroperbenzoic acid / CH₂Cl₂ / 0.33 h / Ambient temperature

With sodium hydroxide; copper(I) bromide dimethylsulfide complex; boron trifluoride diethyl etherate; N-benzyl-N,N,N-triethylammonium chloride; sodium hydride; sodium cyanoborohydride; magnesium; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00093a037