Technology Process of 1-bromo-9-(benzyloxy)tridec-12-ene
There total 4 articles about 1-bromo-9-(benzyloxy)tridec-12-ene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 95 percent / sodium hydride; tetrabutylammonium iodide / dimethylformamide / 18 h / 20 °C
2: 91 percent / bromine; triphenylphosphine / CH2Cl2 / 24 h / 20 °C
With
bromine; tetra-(n-butyl)ammonium iodide; sodium hydride; triphenylphosphine;
In
dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2005.08.027
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: 96 percent / imidazole; 4-dimethylaminopyridine / CH2Cl2 / 3 h / 0 °C
2.1: ozone / methanol / 0.17 h / -50 °C
2.2: 95 percent / dimethyl sulfide / methanol / 1 h / 20 °C
3.1: 100 percent / diethyl ether / 0 - 20 °C
4.1: 95 percent / sodium hydride; tetrabutylammonium iodide / dimethylformamide / 18 h / 20 °C
5.1: 91 percent / bromine; triphenylphosphine / CH2Cl2 / 24 h / 20 °C
With
1H-imidazole; dmap; bromine; tetra-(n-butyl)ammonium iodide; sodium hydride; ozone; triphenylphosphine;
In
methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2005.08.027
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 100 percent / diethyl ether / 0 - 20 °C
2: 95 percent / sodium hydride; tetrabutylammonium iodide / dimethylformamide / 18 h / 20 °C
3: 91 percent / bromine; triphenylphosphine / CH2Cl2 / 24 h / 20 °C
With
bromine; tetra-(n-butyl)ammonium iodide; sodium hydride; triphenylphosphine;
In
diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2005.08.027
