{bis(phenylamido)}{(2,6-Ph₂-C₆H₃O)2}titanium

Base Information

• Chemical Name: {bis(phenylamido)}{(2,6-Ph₂-C₆H₃O)2}titanium
• CAS No.: 129177-03-3
• Molecular Formula: C₄₈H₃₈N₂O₂Ti
• Molecular Weight: 722.722
• Mol file: 129177-03-3.mol

Synonyms:

Chemical Property of {bis(phenylamido)}{(2,6-Ph₂-C₆H₃O)2}titanium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of {bis(phenylamido)}{(2,6-Ph₂-C₆H₃O)2}titanium

There total 1 articles about {bis(phenylamido)}{(2,6-Ph₂-C₆H₃O)2}titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Ti(OC6H3(CH(CH3)2)2)2(C4(C2H5)4) (161240-35-3) → {bis(phenylamido)}{(2,6-Ph2-C6H3O)2}titanium (129177-03-3)

Guidance literature:

With aniline; In hexane; benzene; byproducts: CH(C2H5)(C(C2H5))2CH(C2H5); under N2, addn. of aniline to complex in benzene/hexane, react. for 14 h, pptn.; washed with hexane, dried in vac.; elem. anal.;

DOI:10.1016/S0277-5387(00)84987-6

Reference yield:

{bis(phenylamido)}{(2,6-Ph2-C6H3O)2}titanium (129177-03-3) + 4-pyrrolidin-1-ylpyridine (2456-81-7) → Ti(OC6H3(C6H5)2)2(NC6H5)(NC5H4NC4H8)2

Guidance literature:

In benzene; byproducts: aniline; under N2, addn. of the pyridine to complex in benzene; slow diffusion of hexane into soln., pptn. or evapn., washed with hexane, dried in vac.; elem. anal.;

DOI:10.1016/S0277-5387(00)84987-6

Reference yield:

3,4,7,8-Tetramethyl-o-phenanthrolin (1660-93-1) + {bis(phenylamido)}{(2,6-Ph2-C6H3O)2}titanium (129177-03-3) → Ti(OC6H3(C6H5)2)2(NC6H5)(N2C12H4(CH3)4)

Guidance literature:

In benzene; byproducts: aniline; under N2, addn. of the phenanthroline to complex in benzene, heated for 14 h at 110°C in a sealed flask, slowly cooled to room temp., pptn.; washed with hexane, dried in vac.; elem. anal.;

DOI:10.1016/S0277-5387(00)84987-6

upstream raw materials:

Ti(OC₆H₃(CH(CH₃)2)2)2(C₄(C₂H₅)4)