bis(N-phenylsalicylideneiminato)aluminium(III)di(μ-isopropoxo)di(isopropoxo) aluminium(III)

Base Information

• Chemical Name: bis(N-phenylsalicylideneiminato)aluminium(III)di(μ-isopropoxo)di(isopropoxo) aluminium(III)
• CAS No.: 443286-95-1
• Molecular Formula: C₃₈H₄₈Al₂N₂O₆
• Molecular Weight: 682.772
• Mol file: 443286-95-1.mol

Synonyms:

Chemical Property of bis(N-phenylsalicylideneiminato)aluminium(III)di(μ-isopropoxo)di(isopropoxo) aluminium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(N-phenylsalicylideneiminato)aluminium(III)di(μ-isopropoxo)di(isopropoxo) aluminium(III)

There total 1 articles about bis(N-phenylsalicylideneiminato)aluminium(III)di(μ-isopropoxo)di(isopropoxo) aluminium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.7%

N-phenylsalicylaldimine (779-84-0) + aluminum isopropoxide (555-31-7) → bis(N-phenylsalicylideneiminato)aluminium(III)di(μ-isopropoxo)di(isopropoxo) aluminium(III) (443286-95-1)

Guidance literature:

In benzene; byproducts: (CH3)2CHOH; under anhyd. conditions; mixt. was refluxed for 4 h; solvent was removed; elem. anal.;

DOI:10.1039/b109729f

Reference yield: 99.5%

bis(N-phenylsalicylideneiminato)aluminium(III)di(μ-isopropoxo)di(isopropoxo) aluminium(III) (443286-95-1) + acetone oxime (127-06-0) → bis(N-phenylsalicylideneiminato)aluminium(III)di(μ-isopropoxo)di(isopropoxo) aluminium(III)

Guidance literature:

In benzene; byproducts: C3H7OH; under strictly unhydrous conditions; in 1:2 molar ratio (Al-complex:(CH3)2CNOH in refluxing unhydrous C6H6 for 4 h, C3H7OH fractionated azeotropically with C6H6; excess solvent stripped off under reduced pressure, recrystd. (C6H6/C6H14); elem. anal., detd. by IR, NMR;

DOI:10.1016/S0277-5387(03)00454-6

Reference yield: 99.0%

bis(N-phenylsalicylideneiminato)aluminium(III)di(μ-isopropoxo)di(isopropoxo) aluminium(III) (443286-95-1) + acetone oxime (127-06-0) → bis(N-phenylsalicylideneiminato)aluminium(III)di(μ-isopropoxo)aluminium(III)(isopropoxo)(ONC(CH3)2)

Guidance literature:

In benzene; byproducts: C3H7OH; under strictly unhydrous conditions; in 1:1 molar ratio (Al-complex:(CH3)2CNOH in refluxing unhydrous C6H6 for 4 h, C3H7OH fractionated azeotropically with C6H6; excess solvent stripped off under reduced pressure, recrystd. (C6H6/C6H14); elem. anal., detd. by IR, NMR;

DOI:10.1016/S0277-5387(03)00454-6

upstream raw materials:

N-phenylsalicylaldimine

aluminum isopropoxide

Refernces

• 1、 Sharma, Nikita,Sharma, Rajnish K.,Bohra, Rakesh,Drake, John E.,Hursthouse, Michael B.,Light, Mark E.. "Molecular structure of bis(N-phenylsalicylideneiminato)aluminium-di(μ-isopropoxy)di(isopropoxo) aluminium(III) and its reactions with alkoxyalkanols". . p. 1631 - 1634. Retrieved 2007/10/03.