Methyl dehydro-β-cyclocitrylideneacetate

Base Information

• Chemical Name: Methyl dehydro-β-cyclocitrylideneacetate
• CAS No.: 14398-29-9
• Molecular Formula: C₁₃H₁₈O₂
• Molecular Weight: 206.285
• Mol file: 14398-29-9.mol

Synonyms:

Chemical Property of Methyl dehydro-β-cyclocitrylideneacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Methyl dehydro-β-cyclocitrylideneacetate

There total 3 articles about Methyl dehydro-β-cyclocitrylideneacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-3-(3-Bromo-2,6,6-trimethyl-cyclohex-1-enyl)-acrylic acid methyl ester → Methyl dehydro-β-cyclocitrylideneacetate (14398-29-9)

Guidance literature:

With quinoline;

DOI:10.1080/00021369.1982.10865536

Reference yield:

methyl (E)-3-(2,6,6-trimethylcyclohex-1-en-1-yl)acrylate (14393-46-5,15356-72-6) → Methyl dehydro-β-cyclocitrylideneacetate (14398-29-9)

Guidance literature:

Multi-step reaction with 2 steps

1: NBS

2: quinoline

With quinoline; N-Bromosuccinimide;

DOI:10.1080/00021369.1982.10865536

Reference yield:

→ Methyl dehydro-β-cyclocitrylideneacetate (14398-29-9)

Guidance literature:

aus XII, 1) N-Bromsuccinimid, 2) HBr-Abspaltung mit Chinolin;

upstream raw materials:

methyl (E)-3-(2,6,6-trimethylcyclohex-1-en-1-yl)acrylate

Downstream raw materials:

(2Z,4E)-Methyl 5-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-2,4-pentadienoate

(E)-3-(2,6,6-trimethylcyclohexa-1,3-dien-1-yl)-2-propen-1-al