Tricyclo[6.2.2.0^2,7]dodeca-2⁽⁷⁾,3,5-trien-(9Z)-ylidene-hydrazine

Base Information

• Chemical Name: Tricyclo[6.2.2.0^2,7]dodeca-2⁽⁷⁾,3,5-trien-(9Z)-ylidene-hydrazine
• CAS No.: 957759-67-0
• Molecular Formula: C₁₂H₁₄N₂
• Molecular Weight: 186.257
• Mol file: 957759-67-0.mol

Synonyms:

Chemical Property of Tricyclo[6.2.2.0^2,7]dodeca-2⁽⁷⁾,3,5-trien-(9Z)-ylidene-hydrazine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Tricyclo[6.2.2.0^2,7]dodeca-2⁽⁷⁾,3,5-trien-(9Z)-ylidene-hydrazine

There total 2 articles about Tricyclo[6.2.2.0^2,7]dodeca-2⁽⁷⁾,3,5-trien-(9Z)-ylidene-hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.7%

5,6-benzobicyclo<2.2.2>octen-2-one (13153-76-9,28976-60-5,29073-66-3) → Tricyclo[6.2.2.02,7]dodeca-2(7),3,5-trien-(9Z)-ylidene-hydrazine (957759-67-0)

Guidance literature:

With hydrazine hydrate; triethylamine; In ethanol; for 2h; Heating;

DOI:10.1021/ja00414a015

Reference yield:

Benzobicyclo<2.2.2>octadienon (15100-49-9,31770-11-3,74958-49-9) → Tricyclo[6.2.2.02,7]dodeca-2(7),3,5-trien-(9Z)-ylidene-hydrazine (957759-67-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 6.66 g / hydrogen / 5percent Pd on charcoal / ethanol / 4 h / 25 °C / 2585.7 Torr

2: 86.7 percent / hydrazine hydrate, triethylamine / ethanol / 2 h / Heating

With hydrogen; hydrazine hydrate; triethylamine; palladium on activated charcoal; In ethanol;

DOI:10.1021/ja00414a015

upstream raw materials:

5,6-benzobicyclo<2.2.2>octen-2-one

Benzobicyclo<2.2.2>octadienon