Ni[bis(2-diphenylphosphinoethyl)phenylphosphine](2,4,6-trimercaptotriazine dianion)

Base Information

• Chemical Name: Ni[bis(2-diphenylphosphinoethyl)phenylphosphine](2,4,6-trimercaptotriazine dianion)
• CAS No.: 744202-15-1
• Molecular Formula: C₃₇H₃₄N₃NiP₃S₃
• Molecular Weight: 768.506
• Mol file: 744202-15-1.mol

Synonyms:

Chemical Property of Ni[bis(2-diphenylphosphinoethyl)phenylphosphine](2,4,6-trimercaptotriazine dianion)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ni[bis(2-diphenylphosphinoethyl)phenylphosphine](2,4,6-trimercaptotriazine dianion)

There total 1 articles about Ni[bis(2-diphenylphosphinoethyl)phenylphosphine](2,4,6-trimercaptotriazine dianion) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

nickel(II) chloride hexahydrate + trithiocyanuric acid (638-16-4) + bis(2-diphenylphosphinoethyl)phenylphosphine (23582-02-7) → Ni[bis(2-diphenylphosphinoethyl)phenylphosphine](2,4,6-trimercaptotriazine dianion) (744202-15-1)

Guidance literature:

With Et₃N; In dichloromethane; under N2; soln. of phosphine in CH2Cl2 added to soln. of Ni salt (molar ratio 1:1) in MeOH; solid trimercaptotriazine (1 equv.) added with stirring at room temp.; Et3N (2 equiv.) added; n-BuOH added; N2 bubbled gently; filtered; crystals washed with n-BuOH and Et2O; dried under N2 flow; elem. anal.;

DOI:10.1016/j.ica.2004.01.040

upstream raw materials:

trithiocyanuric acid

bis(2-diphenylphosphinoethyl)phenylphosphine