(R)-2-Methylene-4alpha-phenyl-1,3-dioxolane

Base Information

Chemical Name:(R)-2-Methylene-4alpha-phenyl-1,3-dioxolane
CAS No.:103637-53-2
Molecular Formula:C₁₀H₁₀O₂
Molecular Weight:162.188
Hs Code.:
DSSTox Substance ID:DTXSID101268789
Nikkaji Number:J675.168G
Mol file:103637-53-2.mol

Synonyms:DTXSID101268789;(R)-2-Methylene-4alpha-phenyl-1,3-dioxolane;1,3-Dioxolane, 2-methylene-4-phenyl-, (R)-;103637-53-2

Suppliers and Price of (R)-2-Methylene-4alpha-phenyl-1,3-dioxolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (R)-2-Methylene-4alpha-phenyl-1,3-dioxolane

Chemical Property:

XLogP3:2.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:162.068079557
Heavy Atom Count:12
Complexity:171

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=C1OCC(O1)C2=CC=CC=C2
Isomeric SMILES:C=C1OC[C@H](O1)C2=CC=CC=C2

Technology Process of (R)-2-Methylene-4alpha-phenyl-1,3-dioxolane

There total 2 articles about (R)-2-Methylene-4alpha-phenyl-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (R)-2-Bromomethyl-4-phenyl-[1,3]dioxolane

: 103637-53-2
(R)-2-methylene-4-phenyl-1,3-dioxolane

Guidance literature:: With potassium hydroxide; tetrabutylammomium bromide; at 75 ℃; for 1h; Irradiation;
DOI:10.1080/00397919308009850

Reference yield:

: 16355-00-3
(R)-1-phenyl-1,2-ethanediol

: 103637-53-2
(R)-2-methylene-4-phenyl-1,3-dioxolane

Guidance literature:: Multi-step reaction with 2 steps

1: Dowex 50 (H⁺) / 1 h / 120 °C

2: KOH, TBAB / 1 h / 75 °C / Irradiation

With potassium hydroxide; Dowex 50 (H⁺); tetrabutylammomium bromide;
DOI:10.1080/00397919308009850

Reference yield:

: 103637-53-2
(R)-2-methylene-4-phenyl-1,3-dioxolane

: (S)-5-Oxo-3,5-diphenyl-pentanoic acid (R)-2-hydroxy-2-phenyl-ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 0.05 h / Irradiation

2: 64 percent / Dowex 50(H+) / 1,2-dichloro-benzene / 2 h / 150 °C

With Dowex 50(H+); In 1,2-dichloro-benzene;
DOI:10.1021/jo00118a037