Technology Process of 7,10-Anhydro-6-deoxy-7-C-methyl-1,3,4,8,9,11-hexa-O-benzyl-D-gluco-D-lyxo-5-ulofuranose
There total 10 articles about 7,10-Anhydro-6-deoxy-7-C-methyl-1,3,4,8,9,11-hexa-O-benzyl-D-gluco-D-lyxo-5-ulofuranose which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 100 percent / tetrahydrofuran; diethyl ether / 0.08 h / -78 °C
2: 1.) titanocene dichloride, 2.) pyridine / 1.) toluene, -60 deg C, 72 h, 2.) dry THF, dry toluene, - 60 deg C, 2 h then -20 deg C, 1.5 h
3: BF3*OEt2 / acetonitrile / 0 °C
With
pyridine; titanocene dichloride;
boron trifluoride diethyl etherate;
In
tetrahydrofuran; diethyl ether; acetonitrile;
DOI:10.1021/jo00030a047
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 100 percent / tetrahydrofuran; diethyl ether / 0.08 h / -78 °C
2: 1.) titanocene dichloride, 2.) pyridine / 1.) toluene, -60 deg C, 72 h, 2.) dry THF, dry toluene, - 60 deg C, 2 h then -20 deg C, 1.5 h
3: BF3*OEt2 / acetonitrile / 0 °C
With
pyridine; titanocene dichloride;
boron trifluoride diethyl etherate;
In
tetrahydrofuran; diethyl ether; acetonitrile;
DOI:10.1021/jo00030a047
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 1.) titanocene dichloride, 2.) pyridine / 1.) toluene, -60 deg C, 72 h, 2.) dry THF, dry toluene, - 60 deg C, 2 h then -20 deg C, 1.5 h
2: BF3*OEt2 / acetonitrile / 0 °C
With
pyridine; titanocene dichloride;
boron trifluoride diethyl etherate;
In
acetonitrile;
DOI:10.1021/jo00030a047
