5-[4-(5-hydroxypentyloxy)phenyl]-10,15,20-tri-p-tolylporphininatozinc

Base Information

• Chemical Name: 5-[4-(5-hydroxypentyloxy)phenyl]-10,15,20-tri-p-tolylporphininatozinc
• CAS No.: 1202811-68-4
• Molecular Formula: C₅₂H₄₄N₄O₂Zn
• Molecular Weight: 822.337
• Mol file: 1202811-68-4.mol

Synonyms:

Chemical Property of 5-[4-(5-hydroxypentyloxy)phenyl]-10,15,20-tri-p-tolylporphininatozinc

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-[4-(5-hydroxypentyloxy)phenyl]-10,15,20-tri-p-tolylporphininatozinc

There total 2 articles about 5-[4-(5-hydroxypentyloxy)phenyl]-10,15,20-tri-p-tolylporphininatozinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

5-[4-(5-hydroxypentyloxy)phenyl]-10,15,20-tri-p-tolylporphin → 5-[4-(5-hydroxypentyloxy)phenyl]-10,15,20-tri-p-tolylporphininatozinc (1202811-68-4)

Guidance literature:

With zinc(II) acetylacetonate; In methanol; chloroform; for 1h;

DOI:10.1246/bcsj.82.1280

Reference yield: 83.0%

5-[4-(5-hydroxypentyloxy)phenyl]-10,15,20-tri-p-tolylporphin + zinc(II) acetylacetonate (14024-63-6) → 5-[4-(5-hydroxypentyloxy)phenyl]-10,15,20-tri-p-tolylporphininatozinc (1202811-68-4)

Guidance literature:

In methanol; chloroform; stirring mixt. of porphyrin deriv. and zinc compd. in 9:1 CHCl3/methanolfor 1 h; washing with water, evapn., chromy. (silica gel, CHCl3/methanol (95:5)),recrystn., NMR and MS;

DOI:10.1246/bcsj.82.1280

Reference yield:

5-[4-(5-hydroxypentyloxy)phenyl]-10,15,20-tri-p-tolylporphininatozinc (1202811-68-4) + 2-cyanoethyl-N,N-(diisopropylamino)chlorophosphine (124482-92-4,89992-70-1) → Znpor phosphoramidite (1416044-63-7)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In dichloromethane; mixing zinc compd. with degassed soln. of phosphorus compd. and amine deriv. in CH2Cl2, stirring for 1 h in Ar in dark; concg., chromy. (silica gel, 5% triethylamine in hexane/ethyl acetate), evapn., NMR and MS;

DOI:10.1246/bcsj.82.1280

upstream raw materials:

zinc(II) acetylacetonate

Downstream raw materials:

Znpor phosphoramidite