tricarbonyl((1,2,3,4-η)-5α-(5'-formyl-2'-methoxyphenyl)-1,3-cyclohexadiene)iron(0)

Base Information

• Chemical Name: tricarbonyl((1,2,3,4-η)-5α-(5'-formyl-2'-methoxyphenyl)-1,3-cyclohexadiene)iron(0)
• CAS No.: 557762-79-5
• Molecular Formula: C₁₇H₁₄FeO₅
• Molecular Weight: 354.142

Synonyms:

Chemical Property of tricarbonyl((1,2,3,4-η)-5α-(5'-formyl-2'-methoxyphenyl)-1,3-cyclohexadiene)iron(0)

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Technology Process of tricarbonyl((1,2,3,4-η)-5α-(5'-formyl-2'-methoxyphenyl)-1,3-cyclohexadiene)iron(0)

There total 1 articles about tricarbonyl((1,2,3,4-η)-5α-(5'-formyl-2'-methoxyphenyl)-1,3-cyclohexadiene)iron(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

tricarbonyl[(1,2,3,4,5-η)-1,3-cyclohexadienyl]iron(1+) hexafluorophosphate(1-) + CH3OC6H3(Br)C3H5O2 → tricarbonyl((1,2,3,4-η)-5α-(5'-formyl-2'-methoxyphenyl)-1,3-cyclohexadiene)iron(0) (557762-79-5)

Guidance literature:

With hydrogenchloride; n-butyllithium; copper(I) bromide dimethylsulfide complex; In ethanol; (N2) stirring of C10H11O3Br/THF and n-BuLi/hexane at -78°C for 1 h, addn. of CuBr*Me2S at -40°C; stirring for 1 h at -30°C;addn. of FeC9H7O3PF6 at -78°C; stirring for 2 h, addn. of HCl/Et OH at -10°C; stirring for 0.5h; dilution with water, extn. with ether, drying of combined extracts over MgSO4, concn. under reduced pressure, chromy. on silica gel, elution with a mixt. of hexane/ethyl acetate (5:1), kugelrohr distn., chromy., as oil; elem. anal.;

DOI:10.1016/S0022-328X(02)02146-0

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