bis(diethylamido)[((cyclohexylphosphido-κP)dimethylsilyl)-η5-tetramethylcyclopentadienyl]zirconium

Base Information

• Chemical Name: bis(diethylamido)[((cyclohexylphosphido-κP)dimethylsilyl)-η5-tetramethylcyclopentadienyl]zirconium
• CAS No.: 473435-87-9
• Molecular Formula: C₂₅H₄₉N₂PSiZr
• Molecular Weight: 527.961
• Mol file: 473435-87-9.mol

Synonyms:

Chemical Property of bis(diethylamido)[((cyclohexylphosphido-κP)dimethylsilyl)-η5-tetramethylcyclopentadienyl]zirconium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(diethylamido)[((cyclohexylphosphido-κP)dimethylsilyl)-η5-tetramethylcyclopentadienyl]zirconium

There total 1 articles about bis(diethylamido)[((cyclohexylphosphido-κP)dimethylsilyl)-η5-tetramethylcyclopentadienyl]zirconium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

(C5(CH3)4)Si(CH3)2P(C6H11)(2-)*2Li(1+)=(C5(CH3)4Li)Si(CH3)2P(Li)(C6H11) + bis(diethylamido)-dichloridozirconium(lV)-bis(tetrahydrofurane) (173862-78-7) → bis(diethylamido)[((cyclohexylphosphido-κP)dimethylsilyl)-η5-tetramethylcyclopentadienyl]zirconium (473435-87-9)

Guidance literature:

In tetrahydrofuran; under Ar; a soln. of Zr complex in C4H8O was added to a suspn. of the dilithium salt in C4H8O at -78°C, the mixt. was warmed to 25°C and stirred for 4 h; the solvent was removed in vac., the residue was treated with pentane, ppt. was filtered, the solvent was evapd.; elem. anal.;

DOI:10.1021/om0200959

upstream raw materials:

bis(diethylamido)-dichloridozirconium(lV)-bis(tetrahydrofurane)