(η(5)-pentamethylcyclopentadienyl)(η(5)-1,2,3-triphenylcyclopentadienyl)ruthenium

Base Information

Chemical Name:(η(5)-pentamethylcyclopentadienyl)(η(5)-1,2,3-triphenylcyclopentadienyl)ruthenium
CAS No.:119071-18-0
Molecular Formula:C₃₃H₃₂Ru
Molecular Weight:529.687
Hs Code.:

Synonyms:

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Chemical Property of (η(5)-pentamethylcyclopentadienyl)(η(5)-1,2,3-triphenylcyclopentadienyl)ruthenium

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Technology Process of (η(5)-pentamethylcyclopentadienyl)(η(5)-1,2,3-triphenylcyclopentadienyl)ruthenium

There total 5 articles about (η(5)-pentamethylcyclopentadienyl)(η(5)-1,2,3-triphenylcyclopentadienyl)ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 126821-58-7
chloro(pentamethylcyclopentadienyl)ruthenium(II) tetramer

: 171856-68-1
trans-3-(β0deuteriovinyl)-1,2,3-triphenyl-1-cyclopropene

: 119071-18-0
(η(5)-pentamethylcyclopentadienyl)(η(5)-1,2,3-triphenylcyclopentadienyl)ruthenium

Guidance literature:: In dichloromethane; N2-atmosphere; equimolar amts., stirring overnight; evapn., extn. (petroleum ether), evapn., addn. of ether, evapn.; NMR spectroscopy;

Reference yield: 82.0%

: 171856-72-7
[tris(acetonitrile)(η⁵-1,2,3,4,5-pentamethylcyclopentadienyl)ruthenium(II)][tetrafluoroborate]

: 62747-62-0
1,2,3-triphenyl-3-vinyl-1-cyclopropene

: 119071-18-0
(η(5)-pentamethylcyclopentadienyl)(η(5)-1,2,3-triphenylcyclopentadienyl)ruthenium

Guidance literature:: In dichloromethane; N2-atmosphere; stirring suspension of Ru-complex and cyclopropene (1.1 equiv.) overnight at room temp.; evapn., extn. (petroleum ether), evapn.; NMR spectroscopy;

Reference yield: 65.0%

: 126821-58-7
chloro(pentamethylcyclopentadienyl)ruthenium(II) tetramer

: 62747-62-0
1,2,3-triphenyl-3-vinyl-1-cyclopropene

: 119071-18-0
(η(5)-pentamethylcyclopentadienyl)(η(5)-1,2,3-triphenylcyclopentadienyl)ruthenium

Guidance literature:: In tetrahydrofuran; mixt. stirred (inert atmosphere, room temp, overnight or <5 h), color of soln. changed from orange to golden yellow; solvent removed (vac.), residue extd. with hexanes, recrystd. from Et2O/hexane; elem. anal.;
DOI:10.1021/om00106a023