(Rh(CF₃COCHCOCF₃)(CO)(P(C₆H₅)3))

Base Information

Chemical Name:(Rh(CF₃COCHCOCF₃)(CO)(P(C₆H₅)3))
CAS No.:76136-85-1
Molecular Formula:C₂₄H₁₆F₆O₃PRh
Molecular Weight:600.259
Hs Code.:

(Rh(CF<sub>3</sub>COCHCOCF<sub>3</sub>)(CO)(P(C<sub>6</sub>H<sub>5</sub>)3))

Synonyms:

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Chemical Property of (Rh(CF₃COCHCOCF₃)(CO)(P(C₆H₅)3))

Chemical Property:

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Technology Process of (Rh(CF₃COCHCOCF₃)(CO)(P(C₆H₅)3))

There total 2 articles about (Rh(CF₃COCHCOCF₃)(CO)(P(C₆H₅)3)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

: 17185-29-4
carbonylhydridetris(triphenylphosphine)rhodium(I)

: 1522-22-1
1,1,1,5,5,5-hexafluoroacetylacetone

: 76136-85-1
Rh(hexafluoroacetylacetone)(CO)PPh₃

: 76189-27-0
Rh(CF₃COCHCOCF₃)(CO)(P(C₆H₅)3)2

Guidance literature:: In toluene; equimolar mixt. of Rh-complex and ligand in toluene heated for 30 min at 80°C; evapd. onto silica gel, chromd. (silica gel column), eluted with hexane-benzene and pure benzene, recrystd. from EtOH; elem. anal.;
DOI:10.1021/ic50218a076

Reference yield:

: 18517-12-9
(Rh(CF₃COCHCOCF₃)(CO)2)

: 76136-85-1
(Rh(CF₃COCHCOCF₃)(CO)(P(C₆H₅)3))

Guidance literature:: With triphenylphosphine; In further solvent(s); to soln. (Rh(HFAA)(CO)2) in petroleumbenzine (b.p. 50-70°C) added equimolar amt. PPh3 and mixt. briefly boiled with activated charcoal; filtrate slowly evapd.;
DOI:10.1016/S0020-1693(00)82403-2

Reference yield:

: 76136-85-1
(Rh(CF₃COCHCOCF₃)(CO)(P(C₆H₅)3))

: (Rh(hexafluoroacetylacetone)(CH₃)(I)(CO)(PPh₃))

Guidance literature:: With methyl iodide; In 1,2-dichloro-ethane; react. (Rh(HFAA)(CO)(PPh3)) with MeI in 1,2-dichloroethane soln. at 24.6-34.7°C; not isolated; identified by IR spectra; Kinetics;
DOI:10.1016/S0020-1693(00)82403-2