[Ir(2,2'-bipyridine)H₂(PPh₃)₂]PF₆

Base Information

• Chemical Name: [Ir(2,2'-bipyridine)H₂(PPh₃)₂]PF₆
• CAS No.: 110373-39-2
• Molecular Formula: C₄₆H₄₀IrN₂P₂*F₆P
• Molecular Weight: 1019.97
• Mol file: 110373-39-2.mol

Synonyms:

Chemical Property of [Ir(2,2'-bipyridine)H₂(PPh₃)₂]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [Ir(2,2'-bipyridine)H₂(PPh₃)₂]PF₆

There total 2 articles about [Ir(2,2'-bipyridine)H₂(PPh₃)₂]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

ammonium hexafluorophosphate + {Ir(H)2(C10H8N2)(P(C6H5)3)2}(1+)*BF4(1-)={Ir(H)2(C10H8N2)(P(C6H5)3)2}{BF4} (348112-79-8,102538-90-9) → [Ir(2,2'-bipyridine)H2(PPh3)2]PF6 (110373-39-2)

Guidance literature:

In dichloromethane; addn. of excess of NH4PF6 soln. in CH3OH to CH2Cl2 soln. of (Ir(H)2(bpy)(P(C6H5)3)2)BF4, stirring for 30 min, reduction of volume, partial pptn., further pptn. by addn. of (C2H5)2O;; washing with (C2H5)2O, redissolving in small amt. of CH2Cl2, filtration through frit, repptn. with (C2H5)O, drying under stream of N2;;

Reference yield:

potassium hexafluorophosphate (17084-13-8) + [Ir(2,2'-bipyridine)H2(PPh3)2]Cl → [Ir(2,2'-bipyridine)H2(PPh3)2]PF6 (110373-39-2)

Guidance literature:

In methanol; at 80 ℃; for 0.0833333h; Microwave irradiation;

DOI:10.1021/acs.cgd.6b00810

upstream raw materials:

{Ir(H)2(C₁₀H₈N₂)(P(C₆H₅)3)2}⁽¹⁺⁾*BF₄^(1-)={Ir(H)2(C₁₀H₈N₂)(P(C₆H₅)3)2}{BF₄}

potassium hexafluorophosphate