Au(η2-2-butyne)(P(t-Bu)2(o-biphenyl)(SbF6)

Base Information

• Chemical Name: Au(η2-2-butyne)(P(t-Bu)2(o-biphenyl)(SbF6)
• CAS No.: 1293385-86-0
• Molecular Formula: C₂₄H₃₃AuP*F₆Sb
• Molecular Weight: 785.207
• Mol file: 1293385-86-0.mol

Synonyms:

Chemical Property of Au(η2-2-butyne)(P(t-Bu)2(o-biphenyl)(SbF6)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Au(η2-2-butyne)(P(t-Bu)2(o-biphenyl)(SbF6)

There total 3 articles about Au(η2-2-butyne)(P(t-Bu)2(o-biphenyl)(SbF6) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

silver hexafluoroantimonate (26042-64-8) + dimethylacetylene (503-17-3) + 2-(di-tert-butylphosphino)-1,1'-biphenylgold(I) chloride (854045-93-5) → Au(η2-2-butyne)(P(t-Bu)2(o-biphenyl)(SbF6) (1293385-86-0)

Guidance literature:

In dichloromethane; byproducts: AgCl; N2, Schlenk techniques, glovebox; mixt. stirred in sealed flask at room temp. for 10 min; suspn. filtered through Celite, which was fushed with CH2Cl2, filtrate concd., diluted with hexane, cooled at 4 °C for 24 h; elem. anal.;

DOI:10.1016/j.jorganchem.2010.09.055

Reference yield:

dimethylacetylene (503-17-3) + Au(NC-3,5-C6H3(CF3)2)(P(t-Bu)2(o-biphenyl)(SbF6) (1201271-39-7) → Au(η2-2-butyne)(P(t-Bu)2(o-biphenyl)(SbF6) (1293385-86-0)

Guidance literature:

In dichloromethane-d2; byproducts: NCC6H3(CF3)2; Schlenk technique or glovebox, N2; 2-butyne added via gas tight syringe to NMR tube with soln. of Au-complex at -60 °C, tube shaken, placed in the probe of NMR spectrometer cooled at -60 °C, equilibrated for 10 min; detd. by NMR;

DOI:10.1016/j.jorganchem.2010.09.055

Reference yield:

dimethylacetylene (503-17-3) + Au(NC-3,5-C6H3(CF3)2)(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)(SbF6) → Au(η2-2-butyne)(P(t-Bu)2(o-biphenyl)(SbF6) (1293385-86-0)

Guidance literature:

In dichloromethane-d2; byproducts: NCC6H3(CF3)2; Schlenk technique or glovebox, N2; 2-butyne added via gas tight syringe to NMR tube with soln. of Au-complex at -60 °C, tube shaken, placed in the probe of NMR spectrometer cooled at -60 °C, equilibrated for 10 min; detd. by NMR;

DOI:10.1016/j.jorganchem.2010.09.055

upstream raw materials:

silver hexafluoroantimonate

dimethylacetylene

2-(di-tert-butylphosphino)-1,1'-biphenylgold(I) chloride

Au(NC-3,5-C₆H₃(CF₃)2)(P(t-Bu)2(o-biphenyl)(SbF₆)

Downstream raw materials:

Au(η2-2-methyl-2-butene)(P(t-Bu)2(o-biphenyl)(SbF6)

Au(NC-3,5-C₆H₃(CF₃)2)(P(t-Bu)2(o-biphenyl)(SbF₆)