benzyl(2,2'-thiobis(6-tert-butyl-4-methylphenolato))(η5-1,3-bis(trimethylsilyl)cyclopentadienyl)titanium

Base Information

• Chemical Name: benzyl(2,2'-thiobis(6-tert-butyl-4-methylphenolato))(η5-1,3-bis(trimethylsilyl)cyclopentadienyl)titanium
• CAS No.: 342773-47-1
• Molecular Formula: C₄₀H₅₆O₂SSi₂Ti
• Molecular Weight: 705
• Mol file: 342773-47-1.mol

Synonyms:

Chemical Property of benzyl(2,2'-thiobis(6-tert-butyl-4-methylphenolato))(η5-1,3-bis(trimethylsilyl)cyclopentadienyl)titanium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl(2,2'-thiobis(6-tert-butyl-4-methylphenolato))(η5-1,3-bis(trimethylsilyl)cyclopentadienyl)titanium

There total 1 articles about benzyl(2,2'-thiobis(6-tert-butyl-4-methylphenolato))(η5-1,3-bis(trimethylsilyl)cyclopentadienyl)titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

chloro(2,2'-thiobis(6-tert-butyl-4-methylphenolato))(η5-1,3-bis(trimethylsilyl)cyclopentadienyl)titanium (342773-45-9) + benzylmagnesium chloride (6921-34-2) → benzyl(2,2'-thiobis(6-tert-butyl-4-methylphenolato))(η5-1,3-bis(trimethylsilyl)cyclopentadienyl)titanium (342773-47-1)

Guidance literature:

In tetrahydrofuran; diethyl ether; under Ar, standard Schlenk or glove-box techniques; BzMgCl soln. in THF added to soln. of Ti complex in Et2O at -78°C; stirred for 16 h at room temp.; volatiles removed in vac.; extd. with hexane; solvent removed; recrystd.from pentane at -30°C; elem. anal.;

DOI:10.1016/S0022-328X(00)00846-9

upstream raw materials:

chloro(2,2'-thiobis(6-tert-butyl-4-methylphenolato))(η5-1,3-bis(trimethylsilyl)cyclopentadienyl)titanium

benzylmagnesium chloride