trans-Ph₂bis(Et₂Phphosphine)palladium(II)

Base Information

Chemical Name:trans-Ph₂bis(Et₂Phphosphine)palladium(II)
CAS No.:83947-33-5
Molecular Formula:C₃₂H₄₀P₂Pd
Molecular Weight:593.037
Hs Code.:

trans-Ph<sub>2</sub>bis(Et<sub>2</sub>Phphosphine)palladium(II)

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-Ph₂bis(Et₂Phphosphine)palladium(II)

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Technology Process of trans-Ph₂bis(Et₂Phphosphine)palladium(II)

There total 2 articles about trans-Ph₂bis(Et₂Phphosphine)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 40791-49-9,29484-77-3,29484-69-3
PdCl₂(PEt₂Ph)2

: 591-51-5
phenyllithium

: 83947-33-5
trans-Ph₂bis(Et₂Phphosphine)palladium(II)

Guidance literature:: In diethyl ether; an ether soln. of PhLi was added carefully under inert atmosphere to a suspn. of Pd-complex in ether at -75°C, mixt. was stirred for 40 min at -75°C; ppt. was filtered, washed with cold Et2O, recrystd. from acetone; elem.anal.;
DOI:10.1021/om00074a007

Reference yield:

: Al(OC₂H₅)(C₆H₅)2

: palladium(II) acetylacetonate

: 1605-53-4
diethyl-phenyl-phosphine

: 83947-33-5
trans-Ph₂bis(Et₂Phphosphine)palladium(II)

Guidance literature:: In diethyl ether;

Reference yield:

: 83947-33-5
trans-Ph₂bis(Et₂Phphosphine)palladium(II)

: 917-54-4
methyllithium

: 83947-31-3
dilithium trans-dimethyldiphenylpalladate(II)

Guidance literature:: In diethyl ether; byproducts: diethyl(phenyl)phosphine; 2 equiv of MeLi was added at -75°C under inert atmosphere to a soln. of Pd-complex in Et2O, reaction was monitored by (1)H NMR spectra at room temp.; equil. reaction; not isolated; (1)H NMR spectral data;
DOI:10.1021/om00074a007