dichloro[dimethylbis(diphenylphosphino)tetrathiafulvalene]palladium(II)

Base Information

• Chemical Name: dichloro[dimethylbis(diphenylphosphino)tetrathiafulvalene]palladium(II)
• CAS No.: 701208-67-5
• Molecular Formula: C₃₂H₂₆Cl₂P₂PdS₄
• Molecular Weight: 778.096
• Mol file: 701208-67-5.mol

Synonyms:

Chemical Property of dichloro[dimethylbis(diphenylphosphino)tetrathiafulvalene]palladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of dichloro[dimethylbis(diphenylphosphino)tetrathiafulvalene]palladium(II)

There total 1 articles about dichloro[dimethylbis(diphenylphosphino)tetrathiafulvalene]palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

3,4-bis(diphenylphosphino)-3',4'-dimethyl-2,2',5,5'-tetrathiafulvalene (141858-24-4) + palladium dichloride → dichloro[dimethylbis(diphenylphosphino)tetrathiafulvalene]palladium(II) (701208-67-5)

Guidance literature:

In chloroform; PdCl2 and ligand were suspended in CHCl3, refluxed overnight under N2; cooled, filtered, cond., Et2O was added, washed with Et2O, dried under vac.; elem. anal.;

DOI:10.1021/ic035447y

Reference yield: 46.0%

dichloro[dimethylbis(diphenylphosphino)tetrathiafulvalene]palladium(II) (701208-67-5) + diethyl ether (60-29-7,927820-24-4) + thallium(I) triflate (73491-36-8) → dichloro[dimethylbis(diphenylphosphino)tetrathiafulvalene]palladium(II) thallium(I) triflate adduct*diethyl ether

Guidance literature:

In dichloromethane; Pd-complex and TlOTf were suspended in CH2Cl2, stirred for 18 h under N2; filtered, concd., Et2O was slow diffused; elem. anal.;

DOI:10.1021/ic035447y

upstream raw materials:

3,4-bis(diphenylphosphino)-3',4'-dimethyl-2,2',5,5'-tetrathiafulvalene