C₃₇H₅₁NO₆SSi₂

Base Information

Chemical Name:C₃₇H₅₁NO₆SSi₂
CAS No.:1268261-86-4
Molecular Formula:C₃₇H₅₁NO₆SSi₂
Molecular Weight:694.052
Hs Code.:

C<sub>37</sub>H<sub>51</sub>NO<sub>6</sub>SSi<sub>2</sub>

Synonyms:

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Chemical Property of C₃₇H₅₁NO₆SSi₂

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Technology Process of C₃₇H₅₁NO₆SSi₂

There total 10 articles about C₃₇H₅₁NO₆SSi₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

: 1268261-80-8
C₃₇H₅₃NO₆SSi₂

: 1268261-86-4
C₃₇H₅₁NO₆SSi₂

: C₃₇H₅₁NO₆SSi₂

: 1268261-85-3
C₃₇H₅₁NO₆SSi₂

Guidance literature:: With bis-[(trifluoroacetoxy)iodo]benzene; In acetonitrile; at -5 - 0 ℃; for 0.5h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/anie.201006367

Reference yield:

: 1268261-69-3
C₁₇H₁₆F₃NO₇S

: 1268261-86-4
C₃₇H₅₁NO₆SSi₂

: C₃₇H₅₁NO₆SSi₂

: 1268261-85-3
C₃₇H₅₁NO₆SSi₂

Guidance literature:: Multi-step reaction with 7 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / tetrahydrofuran; water / 2.5 h / 70 °C / Inert atmosphere

2: palladium 10% on activated carbon; hydrogen / ethanol / 1.5 h / 25 °C

3: pyridine / dichloromethane / 12 h / 25 °C / Inert atmosphere

4: water; acetic acid / 60 h / 20 °C / Inert atmosphere

5: 2,6-dimethylpyridine / dichloromethane / 0 - 20 °C / Inert atmosphere

6: 20% palladium(II) hydroxide on carbon; hydrogen / ethyl acetate / 0.33 h / 20 °C

7: bis-[(trifluoroacetoxy)iodo]benzene / acetonitrile / 0.5 h / -5 - 0 °C / Inert atmosphere

With pyridine; 2,6-dimethylpyridine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 20% palladium(II) hydroxide on carbon; palladium 10% on activated carbon; water; hydrogen; sodium carbonate; acetic acid; bis-[(trifluoroacetoxy)iodo]benzene; In tetrahydrofuran; ethanol; dichloromethane; water; ethyl acetate; acetonitrile; 1: Suzuki-Miyaura reaction;
DOI:10.1002/anie.201006367

Reference yield:

: 1268261-71-7
C₃₁H₃₁NO₇

: 1268261-86-4
C₃₇H₅₁NO₆SSi₂

: C₃₇H₅₁NO₆SSi₂

: 1268261-85-3
C₃₇H₅₁NO₆SSi₂

Guidance literature:: Multi-step reaction with 6 steps

1: palladium 10% on activated carbon; hydrogen / ethanol / 1.5 h / 25 °C

2: pyridine / dichloromethane / 12 h / 25 °C / Inert atmosphere

3: water; acetic acid / 60 h / 20 °C / Inert atmosphere

4: 2,6-dimethylpyridine / dichloromethane / 0 - 20 °C / Inert atmosphere

5: 20% palladium(II) hydroxide on carbon; hydrogen / ethyl acetate / 0.33 h / 20 °C

6: bis-[(trifluoroacetoxy)iodo]benzene / acetonitrile / 0.5 h / -5 - 0 °C / Inert atmosphere

With pyridine; 2,6-dimethylpyridine; 20% palladium(II) hydroxide on carbon; palladium 10% on activated carbon; water; hydrogen; acetic acid; bis-[(trifluoroacetoxy)iodo]benzene; In ethanol; dichloromethane; ethyl acetate; acetonitrile;
DOI:10.1002/anie.201006367