[(((trimethylsilyl)2N)2La(THF))2(μ-SPh)(μ-Cl)]*C7H8

Base Information

Chemical Name:[(((trimethylsilyl)2N)2La(THF))2(μ-SPh)(μ-Cl)]*C7H8
CAS No.:880763-26-8
Molecular Formula:C₇H₈*C₃₈H₉₃ClLa₂N₄O₂SSi₈
Molecular Weight:1300.34
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [(((trimethylsilyl)2N)2La(THF))2(μ-SPh)(μ-Cl)]*C7H8

Chemical Property:

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Technology Process of [(((trimethylsilyl)2N)2La(THF))2(μ-SPh)(μ-Cl)]*C7H8

There total 1 articles about [(((trimethylsilyl)2N)2La(THF))2(μ-SPh)(μ-Cl)]*C7H8 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 808772-25-0
[(Me₃Si)₂N]₃La(μ-Cl)Li(THF)₃

: 108-98-5
thiophenol

: 108-88-3,15644-74-3,16713-13-6
toluene

: 880763-26-8
[(((trimethylsilyl)2N)2La(THF))2(μ-SPh)(μ-Cl)]*C7H8

: [((trimethylsilyl)2N)2La₅O(SPh)10LiCl₂(THF)6]*C₇H₈

Guidance literature:: In tetrahydrofuran; hexane; to soln. La complex in THF soln. PhSH in hexane was added and stirred overnight at room temp.; soln. was concd. to dryness in vacuo, residue was extd. with toluene, concd., and cooled to -18°C for several days, ppt. was filtered, washed with hexane, and dried in vacuo; elem. anal.;
DOI:10.1021/ic052073v

Reference yield: 5.0%

: 880763-26-8
[(((trimethylsilyl)2N)2La(THF))2(μ-SPh)(μ-Cl)]*C7H8

: 7732-18-5
water

: lithium chloride

: tris(bis(trimethylsilyl)amido)lanthanum(III)

: [((trimethylsilyl)2N)2La₅O(SPh)10LiCl₂(THF)6]*C₇H₈

Guidance literature:: In tetrahydrofuran; to soln. La complex and LiCl in THF soln. 1/6 equiv. H2O in THF was added and stirred overnight at room temp.; soln. was concd. in vacuo, hexane was added, stirred for 15 min, evapd. in vacuo, washed with hexane, extd. with hot hexane and toluene (35°C), concd., cooled to 2°C, ppt. was filtered, washed with hexane, dried in vacuo; elem. anal.;
DOI:10.1021/ic052073v