{RhAu(CO)(P(C6H5)3)2(η5-C2B9H9(CH3)2)}

Base Information

Chemical Name:{RhAu(CO)(P(C6H5)3)2(η5-C2B9H9(CH3)2)}
CAS No.:135157-53-8
Molecular Formula:C₄₁H₄₅AuB₉OP₂Rh
Molecular Weight:1012.93
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of {RhAu(CO)(P(C6H5)3)2(η5-C2B9H9(CH3)2)}

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Technology Process of {RhAu(CO)(P(C6H5)3)2(η5-C2B9H9(CH3)2)}

There total 2 articles about {RhAu(CO)(P(C6H5)3)2(η5-C2B9H9(CH3)2)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 15318-33-9,16353-77-8,13938-94-8
trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I)

: {NEt₄}{10-endo-{Au(PPh₃)}-7,8-nido-C₂B₉H₉Me₂}

: 135157-53-8
{RhAu(CO)(P(C6H5)3)2(η5-C2B9H9(CH3)2)}

Guidance literature:: With TlBF₄; In tetrahydrofuran; byproducts: TlCl; stirring carborane, Rh complex and TlBF4 in THF at room temp. for 12 h under dry O2-free N2;; removal of solvent in vac.; suspending in CH2Cl2; filtration through Celite pad; reduction of volume in vac.; chromatography on alumina with CH2Cl2/light petroleum; removal of solvent in vac.; crystn. from CH2Cl2/light petroleum;;
DOI:10.1039/DT9930001073

Reference yield: 69.0%

: 14243-64-2
(triphenylphosphine)gold(I) chloride

: 135157-57-2
{N(C2H5)4}{Rh(CO)(P(C6H5)3)(η5-C2B9H9(CH3)2)}

: 135157-53-8
{RhAu(CO)(P(C6H5)3)2(η5-C2B9H9(CH3)2)}

Guidance literature:: With TlBF₄; In dichloromethane; mixt. stirred for 1 h, filtered, solvent removed in vac.; dissolved in CH2Cl2, removal of solvent in vac.; elem. anal.;;
DOI:10.1039/DT9910001355