1,4-[RuCl(CO)(PMe₃)3CH=CH]2C₆H₃F

Base Information

• Chemical Name: 1,4-[RuCl(CO)(PMe₃)3CH=CH]2C₆H₃F
• CAS No.: 1146301-54-3
• Molecular Formula: C₃₀H₆₁Cl₂FO₂P₆Ru₂
• Molecular Weight: 931.7
• Mol file: 1146301-54-3.mol

Synonyms:

Chemical Property of 1,4-[RuCl(CO)(PMe₃)3CH=CH]2C₆H₃F

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of 1,4-[RuCl(CO)(PMe₃)3CH=CH]2C₆H₃F

There total 1 articles about 1,4-[RuCl(CO)(PMe₃)3CH=CH]2C₆H₃F which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) + 1,4-diethynyl-2-fluorobenzene (137000-66-9) → 1,4-[RuCl(CO)(PMe3)3CH=CH]2C6H3F (1146301-54-3)

Guidance literature:

In tetrahydrofuran; dichloromethane; (N2); std. Schlenk technique; soln. of diethynylbenzene in CH2Cl2 was slowly added to suspn. of Ru complex in CH2Cl2 at room temp.; stirred for 30 min; soln. of PMe3 in THF was added; stirred for 15 h; filtered through Celite; concd. (vac.); hexane added; filtered; washed (hexane); dried (vac.); elem. anal.;

DOI:10.1021/om900018y

upstream raw materials:

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

1,4-diethynyl-2-fluorobenzene