Mo₂W(CO)12S^(2-)*2(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾={Mo₂W(CO)12S}{(C₆H₅)3PNP(C₆H₅)3}2

Base Information

• Chemical Name: Mo₂W(CO)12S^(2-)*2(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾={Mo₂W(CO)12S}{(C₆H₅)3PNP(C₆H₅)3}2
• CAS No.: 112680-77-0
• Molecular Formula: C₁₂Mo₂O₁₂SW*2C₃₆H₃₀NP₂
• Molecular Weight: 1821.1
• Mol file: 112680-77-0.mol

Synonyms:

Chemical Property of Mo₂W(CO)12S^(2-)*2(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾={Mo₂W(CO)12S}{(C₆H₅)3PNP(C₆H₅)3}2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mo₂W(CO)12S^(2-)*2(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾={Mo₂W(CO)12S}{(C₆H₅)3PNP(C₆H₅)3}2

There total 1 articles about Mo₂W(CO)12S^(2-)*2(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾={Mo₂W(CO)12S}{(C₆H₅)3PNP(C₆H₅)3}2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.5%

sodium hydrogen sulfide + tungsten pentacarbonyl tetrahydrofuran (36477-75-5) + bis(triphenylphosphine)iminium chloride (21050-13-5) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → Mo2W(CO)12S(2-)*2(C6H5)3PNP(C6H5)3(1+)={Mo2W(CO)12S}{(C6H5)3PNP(C6H5)3}2 (112680-77-0)

Guidance literature:

With NaH; In ethanol; NaSH, {PPN}Cl, EtOH stirred (3h), solvent removal, addn. of Mo(CO)6 in THF, stirred overnight, Et2O-addn., {Mo(CO)5SH}PPN pptd., {Mo2(CO)10SH}PPN in soln.; solvent removal, washed with hexane; addn. of THF, NaH, W(CO)5THF, after 1h addn. of{PPN}Cl, EtOH; stirred for 1 h, solvent removal, recrystn. from acetone/diethyl ether; elemental analysis;

upstream raw materials:

tungsten pentacarbonyl tetrahydrofuran

bis(triphenylphosphine)iminium chloride

molybdenum hexacarbonyl

Refernces