(Z)-4-methoxy-1-[1-(4-methoxyphenyl)oct-1-en-1-yl]-2-nitrobenzene

Base Information

Chemical Name:(Z)-4-methoxy-1-[1-(4-methoxyphenyl)oct-1-en-1-yl]-2-nitrobenzene
CAS No.:1370521-20-2
Molecular Formula:C₂₂H₂₇NO₄
Molecular Weight:369.461
Hs Code.:

Synonyms:

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Chemical Property of (Z)-4-methoxy-1-[1-(4-methoxyphenyl)oct-1-en-1-yl]-2-nitrobenzene

Chemical Property:

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Technology Process of (Z)-4-methoxy-1-[1-(4-methoxyphenyl)oct-1-en-1-yl]-2-nitrobenzene

There total 5 articles about (Z)-4-methoxy-1-[1-(4-methoxyphenyl)oct-1-en-1-yl]-2-nitrobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₂H₃₀N₂O₃S

: 58755-70-7
1-iodo-4-methoxy-2-nitrobenzene

: 1370521-20-2
(Z)-4-methoxy-1-[1-(4-methoxyphenyl)oct-1-en-1-yl]-2-nitrobenzene

Guidance literature:: With dichloro bis(acetonitrile) palladium(II); lithium tert-butoxide; XPhos; In 1,4-dioxane; at 90 ℃; for 1h; optical yield given as %de; stereoselective reaction; Inert atmosphere;
DOI:10.1002/ejoc.201101735

Reference yield:

: 629-05-0
n-octyne

: 1370521-20-2
(Z)-4-methoxy-1-[1-(4-methoxyphenyl)oct-1-en-1-yl]-2-nitrobenzene

Guidance literature:: Multi-step reaction with 4 steps

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / 4 h / 20 °C / Inert atmosphere

2: toluene-4-sulfonic acid / ethanol / 0.5 h / 120 °C / Microwave irradiation; Inert atmosphere

3: 0.25 h / 50 °C / Microwave irradiation; Inert atmosphere

4: dichloro bis(acetonitrile) palladium(II); lithium tert-butoxide; XPhos / 1,4-dioxane / 1 h / 90 °C / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; dichloro bis(acetonitrile) palladium(II); copper(l) iodide; toluene-4-sulfonic acid; triethylamine; lithium tert-butoxide; XPhos; In 1,4-dioxane; ethanol; 1: Sonogashira-Linstrumelle coupling;
DOI:10.1002/ejoc.201101735

Reference yield:

: 696-62-8
para-iodoanisole

: 1370521-20-2
(Z)-4-methoxy-1-[1-(4-methoxyphenyl)oct-1-en-1-yl]-2-nitrobenzene

Guidance literature:: Multi-step reaction with 4 steps

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / 4 h / 20 °C / Inert atmosphere

2: toluene-4-sulfonic acid / ethanol / 0.5 h / 120 °C / Microwave irradiation; Inert atmosphere

3: 0.25 h / 50 °C / Microwave irradiation; Inert atmosphere

4: dichloro bis(acetonitrile) palladium(II); lithium tert-butoxide; XPhos / 1,4-dioxane / 1 h / 90 °C / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; dichloro bis(acetonitrile) palladium(II); copper(l) iodide; toluene-4-sulfonic acid; triethylamine; lithium tert-butoxide; XPhos; In 1,4-dioxane; ethanol; 1: Sonogashira-Linstrumelle coupling;
DOI:10.1002/ejoc.201101735