Rh((CH₃)2C₂N₂O₂H)2P(C₆H₅)3CH₂F

Base Information

• Chemical Name: Rh((CH₃)2C₂N₂O₂H)2P(C₆H₅)3CH₂F
• CAS No.: 343248-53-3
• Molecular Formula: C₂₇H₃₁FN₄O₄PRh
• Molecular Weight: 628.445
• Mol file: 343248-53-3.mol

Synonyms:

Chemical Property of Rh((CH₃)2C₂N₂O₂H)2P(C₆H₅)3CH₂F

Chemical Property:

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Technology Process of Rh((CH₃)2C₂N₂O₂H)2P(C₆H₅)3CH₂F

There total 1 articles about Rh((CH₃)2C₂N₂O₂H)2P(C₆H₅)3CH₂F which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

bis((dimethylglyoximato)triphenylphosphine)(Cl)rhodium(III) + R32 (593-70-4) → Rh((CH3)2C2N2O2H)2P(C6H5)3CH2F (343248-53-3)

Guidance literature:

With KOH; NaBH₄; In methanol; to a soln. of complex in methanolic KOH a soln. of NaBH4 in methanolic KOH was added dropwise and stirred for 2 h at 20°C, ClCH2F in methanol was added within 2 min, 4 h (Ar); H2O was added, neutralized with solid CO2, extd. with CH2Cl2, dried (N2SO4), concd., ppt. was dissolved in acetone, repptd. with heptane; elem. anal.;

DOI:10.1016/S0022-328X(00)00886-X

upstream raw materials:

R₃₂