aquadicarbonylhydridobis(triphenylphosphine)ruthenium(II) tetrafluoroborate

Base Information

• Chemical Name: aquadicarbonylhydridobis(triphenylphosphine)ruthenium(II) tetrafluoroborate
• CAS No.: 60020-25-9
• Molecular Formula: BF₄*C₃₈H₃₃O₃P₂Ru
• Molecular Weight: 787.5
• Mol file: 60020-25-9.mol

Synonyms:

Chemical Property of aquadicarbonylhydridobis(triphenylphosphine)ruthenium(II) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of aquadicarbonylhydridobis(triphenylphosphine)ruthenium(II) tetrafluoroborate

There total 1 articles about aquadicarbonylhydridobis(triphenylphosphine)ruthenium(II) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

tetrafluoroboric acid + acetatohydridotris(triphenylphosphine)ruthenium(II) (25087-75-6,311819-28-0,55354-87-5) → aquadicarbonylhydridobis(triphenylphosphine)ruthenium(II) tetrafluoroborate (60020-25-9,78216-70-3)

Guidance literature:

With H₂; CO; In water; acetone; addn. of excess of 42% aq. HBF4 to Ru-complex (under H2), refluxing and passing CO; crystn. on volume reduction, addn. of ether and cooling to -20°C for 24 h, collection, washing (ether), drying (vac.); elem. anal.;

DOI:10.1039/DT9760000719

Reference yield: 65.0%

aquadicarbonylhydridobis(triphenylphosphine)ruthenium(II) tetrafluoroborate (60020-25-9,78216-70-3) → dicarbonylchlorohydridobis(triphenylphosphine)ruthenium(II) (56144-64-0,52555-05-2,32240-58-7)

Guidance literature:

With LiCl; In methanol; N2-atmosphere; refluxing for few min; pptn. on cooling, collection, washing (MeOH, ether), drying (vac.); elem. anal.;

DOI:10.1039/DT9760000719

upstream raw materials:

acetatohydridotris(triphenylphosphine)ruthenium(II)

Downstream raw materials:

dicarbonylchlorohydridobis(triphenylphosphine)ruthenium(II)