cis-triphenylphosphinimine(azidoquinoline) tetracarbonylmolybdenum(O)*monoacetonitrile

Base Information

• Chemical Name: cis-triphenylphosphinimine(azidoquinoline) tetracarbonylmolybdenum(O)*monoacetonitrile
• CAS No.: 135740-68-0
• Molecular Formula: C₂H₃N*C₃₁H₂₁MoN₂O₄P
• Molecular Weight: 653.485
• Mol file: 135740-68-0.mol

Synonyms:

Chemical Property of cis-triphenylphosphinimine(azidoquinoline) tetracarbonylmolybdenum(O)*monoacetonitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-triphenylphosphinimine(azidoquinoline) tetracarbonylmolybdenum(O)*monoacetonitrile

There total 2 articles about cis-triphenylphosphinimine(azidoquinoline) tetracarbonylmolybdenum(O)*monoacetonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

fac-(acetonitrile)2triphenylphosphinetricarbonylmolybdenum (54460-81-0,83057-97-0) + 8-azidoquinoline (50400-06-1) → cis-triphenylphosphinimine(azidoquinoline) tetracarbonylmolybdenum(O)*monoacetonitrile (135740-68-0) + bis(triphenylphosphine)monoacetonitrile tricarbonylmolybdenum (31265-07-3,31265-08-4,82916-66-3) + triphenylphosphine((triphenylphosphinimine)quinoline)tricarbonylmolybdenum (135740-69-1)

Guidance literature:

With CO; In acetonitrile; byproducts: CH3CN; Addn. of Mo-compd. in CH3CN soln. to 8-azidoquinoline at -5°C, soln. was stirred at -5°C for 1 h (N2).; React. is monitored by IR, isolation at room temp., elem. anal.;

Reference yield:

monoacetonitrile(triphenylphosphiniminequinoline) tricarbonylmolybdenum (135740-73-7) → cis-triphenylphosphinimine(azidoquinoline) tetracarbonylmolybdenum(O)*monoacetonitrile (135740-68-0)

Guidance literature:

With CO; In dichloromethane; Passing CO through the soln. for 2 min leads to complete conversion.;

upstream raw materials:

fac-(acetonitrile)2triphenylphosphinetricarbonylmolybdenum

8-azidoquinoline

monoacetonitrile(triphenylphosphiniminequinoline) tricarbonylmolybdenum