(η1-pentamethylcyclopentadienyl)(triphenylphosphine)gold

Base Information

Chemical Name:(η1-pentamethylcyclopentadienyl)(triphenylphosphine)gold
CAS No.:89989-61-7
Molecular Formula:C₂₈H₃₀AuP
Molecular Weight:594.486
Hs Code.:

Synonyms:

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Chemical Property of (η1-pentamethylcyclopentadienyl)(triphenylphosphine)gold

Chemical Property:

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Technology Process of (η1-pentamethylcyclopentadienyl)(triphenylphosphine)gold

There total 1 articles about (η1-pentamethylcyclopentadienyl)(triphenylphosphine)gold which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14243-64-2
(triphenylphosphine)gold(I) chloride

: 51905-34-1
pentamethylcyclopentadienyllithium

: 89989-61-7
(η1-pentamethylcyclopentadienyl)(triphenylphosphine)gold

Guidance literature:: In benzene; an equimol. amt. of Ph3PAuCl was added under N2 to a toluene soln. of LiC5Me5, mixt. was stirred for 1 h at 10°C; evapd. in vacuo, pentane was added, cooled to -78°C, supernatantdecanted, ppt. was suspended in pentane, filtered through Celite, filtrate was concd., cooled to -78°C, crystals were washed with pentane, dried under high vac.; elem. anal.;
DOI:10.1016/S0022-328X(00)99128-9

Reference yield: 49.0%

: 89989-61-7
(η1-pentamethylcyclopentadienyl)(triphenylphosphine)gold

: 105945-08-2
(1,2,3,4,5-pentamethyl-2,4-cyclopentadiene-1-dithiocarboxylato-S⁽¹⁾)bis(triphenylphosphane)gold

Guidance literature:: With CS₂; P(C₆H₅)3; In benzene; addn. of CS2 to a soln. of the C5Me5-phosphane-metal complex and PPh3 at 5°C, stirring for 3 h; removal of the volatiles in vacuo, washing with cold pentane, column chromy., concg., addn. of pentane, storing at 0°C for 24 h, filtration, washing with pentane, drying in vacuo, elem. anal.;

Reference yield:

: 89989-61-7
(η1-pentamethylcyclopentadienyl)(triphenylphosphine)gold

: 536-74-3
phenylacetylene

: phenylethynyl(triphenylphosphine)gold(I)

Guidance literature:: In toluene; a soln. of Au-complex in toluene was treated with an equimol. amt. of PhC2H at -78°C under N2, mixt. was left standing for 3 d; filtered, filtrate was treated with pentane, resulting crystals were washed with pentane and dried under high vac.;
DOI:10.1016/S0022-328X(00)99128-9