2,6-diisopropyl-phenyl-{1-methyl-2-[(1-methyl-2-methylimino-propylidene)hydrazono]propylidene}amine dinickel(II) chloride

Base Information

• Chemical Name: 2,6-diisopropyl-phenyl-{1-methyl-2-[(1-methyl-2-methylimino-propylidene)hydrazono]propylidene}amine dinickel(II) chloride
• CAS No.: 1471999-30-0
• Molecular Formula: C₃₂H₅₀Cl₄N₄Ni₂
• Molecular Weight: 749.968
• Mol file: 1471999-30-0.mol

Synonyms:

Chemical Property of 2,6-diisopropyl-phenyl-{1-methyl-2-[(1-methyl-2-methylimino-propylidene)hydrazono]propylidene}amine dinickel(II) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,6-diisopropyl-phenyl-{1-methyl-2-[(1-methyl-2-methylimino-propylidene)hydrazono]propylidene}amine dinickel(II) chloride

There total 2 articles about 2,6-diisopropyl-phenyl-{1-methyl-2-[(1-methyl-2-methylimino-propylidene)hydrazono]propylidene}amine dinickel(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

(1,2-dimethoxyethane)dichloronickel(II) (29046-78-4) + 2,6-diisopropyl-phenyl-{1-methyl-2-[(1-methyl-2-methylimino-propylidene)hydrazono]propylidene}amine → 2,6-diisopropyl-phenyl-{1-methyl-2-[(1-methyl-2-methylimino-propylidene)hydrazono]propylidene}amine dinickel(II) chloride (1471999-30-0)

Guidance literature:

In dichloromethane; at 20 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1007/s10562-013-1123-2

Reference yield:

2,6-diisopropylbenzenamine (24544-04-5) → 2,6-diisopropyl-phenyl-{1-methyl-2-[(1-methyl-2-methylimino-propylidene)hydrazono]propylidene}amine dinickel(II) chloride (1471999-30-0)

Guidance literature:

Multi-step reaction with 3 steps

1: acetic acid / ethanol / 36 h / 20 °C / Inert atmosphere; Schlenk technique

2: hydrazine hydrate / ethanol / Inert atmosphere; Schlenk technique

3: dichloromethane / 12 h / 20 °C / Inert atmosphere; Schlenk technique

With hydrazine hydrate; acetic acid; In ethanol; dichloromethane;

DOI:10.1007/s10562-013-1123-2

upstream raw materials:

(1,2-dimethoxyethane)dichloronickel(II)

2,6-diisopropylbenzenamine