(-)N-(12-Acetoxy-9,10-dehydrojasmonoyl)-phenylalaninmethylester

Base Information

Chemical Name:(-)N-(12-Acetoxy-9,10-dehydrojasmonoyl)-phenylalaninmethylester
CAS No.:91991-54-7
Molecular Formula:C₂₄H₂₉NO₆
Molecular Weight:427.497
Hs Code.:

Synonyms:

Suppliers and Price of (-)N-(12-Acetoxy-9,10-dehydrojasmonoyl)-phenylalaninmethylester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (-)N-(12-Acetoxy-9,10-dehydrojasmonoyl)-phenylalaninmethylester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (-)N-(12-Acetoxy-9,10-dehydrojasmonoyl)-phenylalaninmethylester

There total 24 articles about (-)N-(12-Acetoxy-9,10-dehydrojasmonoyl)-phenylalaninmethylester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 38996-32-6
5-(tetrahydropyran-2-yloxy)-3-pentyn-1-ol

: 91991-54-7,92076-82-9
(+)N-(12-Acetoxy-9,10-dehydrojasmonoyl)-phenylalaninmethylester

Guidance literature:: Multi-step reaction with 13 steps

1: 93.3 percent / 4-dimethylaminopyridin, pyridin / 2 h / 70 °C

2: 96 percent / Amberlyst 15 (H+) / methanol / 1 h / 45 °C

3: 91.7 percent / phosphortribromid / diethyl ether / 0 °C

4: 90.6 percent / K₂CO₃ / acetone / 20 h / Heating

5: 91.8 percent / NaCN / dimethylsulfoxide / 2 h / 160 °C

6: 81.7 percent / p-toluenesulfonic acid / 8 h / Heating

7: 1.) CaCO₃, Brom; 2.) LiBr, Li₂CO₃ / 1.) CHCl₃, CCl₄, 0 deg C, 30 min; 2.) DMF, reflux, 20 min

8: acetonitrile / 5 h / 55 °C

9: 1.) acetic acid; 2.) triethylamine / 1.) water, THF, RT, 24 h; 2.) 130 deg C, 5 h

10: 5percent NaOH / H₂O / 0.08 h / Heating

11: DMAP / 2 h / 70 °C

12: Oxalylchlorid / benzene / 1 h / Ambient temperature

13: DMAP / benzene / 0.25 h / Heating

With pyridine; dmap; sodium hydroxide; oxalyl dichloride; Amberlyst 15 (H+); sodium cyanide; bromine; phosphorus tribromide; lithium carbonate; potassium carbonate; acetic acid; triethylamine; calcium carbonate; lithium bromide; toluene-4-sulfonic acid; In methanol; diethyl ether; water; dimethyl sulfoxide; acetone; acetonitrile; benzene;
DOI:10.1016/S0040-4020(01)83506-7

Reference yield:

: 38996-32-6
5-(tetrahydropyran-2-yloxy)-3-pentyn-1-ol

: 91991-54-7,92076-82-9
(-)N-(12-Acetoxy-9,10-dehydrojasmonoyl)-phenylalaninmethylester

Guidance literature:: Multi-step reaction with 13 steps

1: 93.3 percent / 4-dimethylaminopyridin, pyridin / 2 h / 70 °C

2: 96 percent / Amberlyst 15 (H+) / methanol / 1 h / 45 °C

3: 91.7 percent / phosphortribromid / diethyl ether / 0 °C

4: 90.6 percent / K₂CO₃ / acetone / 20 h / Heating

5: 91.8 percent / NaCN / dimethylsulfoxide / 2 h / 160 °C

6: 81.7 percent / p-toluenesulfonic acid / 8 h / Heating

7: 1.) CaCO₃, Brom; 2.) LiBr, Li₂CO₃ / 1.) CHCl₃, CCl₄, 0 deg C, 30 min; 2.) DMF, reflux, 20 min

8: acetonitrile / 5 h / 55 °C

9: 1.) acetic acid; 2.) triethylamine / 1.) water, THF, RT, 24 h; 2.) 130 deg C, 5 h

10: 5percent NaOH / H₂O / 0.08 h / Heating

11: DMAP / 2 h / 70 °C

12: Oxalylchlorid / benzene / 1 h / Ambient temperature

13: DMAP / benzene / 0.25 h / Heating

With pyridine; dmap; sodium hydroxide; oxalyl dichloride; Amberlyst 15 (H+); sodium cyanide; bromine; phosphorus tribromide; lithium carbonate; potassium carbonate; acetic acid; triethylamine; calcium carbonate; lithium bromide; toluene-4-sulfonic acid; In methanol; diethyl ether; water; dimethyl sulfoxide; acetone; acetonitrile; benzene;
DOI:10.1016/S0040-4020(01)83506-7

Reference yield:

: 91991-57-0
5-hydroxypent-3-yn-1-yl acetate

: 91991-54-7,92076-82-9
(+)N-(12-Acetoxy-9,10-dehydrojasmonoyl)-phenylalaninmethylester

Guidance literature:: Multi-step reaction with 11 steps

1: 91.7 percent / phosphortribromid / diethyl ether / 0 °C

2: 90.6 percent / K₂CO₃ / acetone / 20 h / Heating

3: 91.8 percent / NaCN / dimethylsulfoxide / 2 h / 160 °C

4: 81.7 percent / p-toluenesulfonic acid / 8 h / Heating

5: 1.) CaCO₃, Brom; 2.) LiBr, Li₂CO₃ / 1.) CHCl₃, CCl₄, 0 deg C, 30 min; 2.) DMF, reflux, 20 min

6: acetonitrile / 5 h / 55 °C

7: 1.) acetic acid; 2.) triethylamine / 1.) water, THF, RT, 24 h; 2.) 130 deg C, 5 h

8: 5percent NaOH / H₂O / 0.08 h / Heating

9: DMAP / 2 h / 70 °C

10: Oxalylchlorid / benzene / 1 h / Ambient temperature

11: DMAP / benzene / 0.25 h / Heating

With dmap; sodium hydroxide; oxalyl dichloride; sodium cyanide; bromine; phosphorus tribromide; lithium carbonate; potassium carbonate; acetic acid; triethylamine; calcium carbonate; lithium bromide; toluene-4-sulfonic acid; In diethyl ether; water; dimethyl sulfoxide; acetone; acetonitrile; benzene;
DOI:10.1016/S0040-4020(01)83506-7