silver 1,3-diphenyl-1,3-propandionate

Base Information

• Chemical Name: silver 1,3-diphenyl-1,3-propandionate
• CAS No.: 15841-27-7
• Molecular Formula: C₁₅H₁₁AgO₂
• Molecular Weight: 331.119
• Mol file: 15841-27-7.mol

Synonyms:

Chemical Property of silver 1,3-diphenyl-1,3-propandionate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of silver 1,3-diphenyl-1,3-propandionate

There total 1 articles about silver 1,3-diphenyl-1,3-propandionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

silver nitrate + 1,3-diphenylpropanedione (120-46-7,61346-73-4) → silver 1,3-diphenyl-1,3-propandionate (15841-27-7)

Guidance literature:

With triethylamine; under N2;

DOI:10.1002/zaac.200500143

Reference yield: 100.0%

tributylphosphine (998-40-3) + silver 1,3-diphenyl-1,3-propandionate (15841-27-7) → (nBu3P)Ag(1,3-diphenyl-1,3-propanedionate) (879555-31-4)

Guidance literature:

In diethyl ether; under N2, Ag-compd. was dissolved in Et2O, 1 equiv. of P-compd. was added, stirring at 25 °C for 2 h; soln. was filtered through silica, volatiles were removed in vac., elem.anal.;

DOI:10.1002/zaac.200500143

Reference yield: 99.0%

tributylphosphine (998-40-3) + silver 1,3-diphenyl-1,3-propandionate (15841-27-7) → (nBu3P)2Ag(1,3-diphenyl-1,3-propanedionate) (879555-32-5)

Guidance literature:

In diethyl ether; under N2, Ag-compd. was dissolved in Et2O, 2 equiv. of P-compd. was added, stirring at 25 °C for 2 h; soln. was filtered through silica, volatiles were removed in vac., elem.anal.;

DOI:10.1002/zaac.200500143

upstream raw materials:

1,3-diphenylpropanedione

Downstream raw materials:

[(η(2)-(Me3Si)2CC)Cu(I)(1,3-diphenyl-1,3-propandionate)]

[(C₆H₄CH₂NMe₂-2)3PCu(I)(1,3-diphenyl-1,3-propandionate)]

(nBu₃P)Ag(1,3-diphenyl-1,3-propanedionate)

(nBu₃P)2Ag(1,3-diphenyl-1,3-propanedionate)

Refernces