3,5-Dinitro-benzoic acid (S)-3-[2-[(1R,3aS,7aR)-1-((R)-5-hydroxy-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-(4E)-ylidene]-eth-(E)-ylidene]-4-methylene-cyclohexyl ester

Base Information

Chemical Name:3,5-Dinitro-benzoic acid (S)-3-[2-[(1R,3aS,7aR)-1-((R)-5-hydroxy-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-(4E)-ylidene]-eth-(E)-ylidene]-4-methylene-cyclohexyl ester
CAS No.:87417-20-7
Molecular Formula:C₃₄H₄₆N₂O₇
Molecular Weight:594.748
Hs Code.:

3,5-Dinitro-benzoic acid (S)-3-[2-[(1R,3aS,7aR)-1-((R)-5-hydroxy-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-(4E)-ylidene]-eth-(E)-ylidene]-4-methylene-cyclohexyl ester

Synonyms:

Suppliers and Price of 3,5-Dinitro-benzoic acid (S)-3-[2-[(1R,3aS,7aR)-1-((R)-5-hydroxy-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-(4E)-ylidene]-eth-(E)-ylidene]-4-methylene-cyclohexyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3,5-Dinitro-benzoic acid (S)-3-[2-[(1R,3aS,7aR)-1-((R)-5-hydroxy-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-(4E)-ylidene]-eth-(E)-ylidene]-4-methylene-cyclohexyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3,5-Dinitro-benzoic acid (S)-3-[2-[(1R,3aS,7aR)-1-((R)-5-hydroxy-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-(4E)-ylidene]-eth-(E)-ylidene]-4-methylene-cyclohexyl ester

There total 17 articles about 3,5-Dinitro-benzoic acid (S)-3-[2-[(1R,3aS,7aR)-1-((R)-5-hydroxy-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-(4E)-ylidene]-eth-(E)-ylidene]-4-methylene-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 1233749-00-2
3β,25-dihydroxy-9,10-secocholesta-5(E),7(E),10(19)-triene

: 99-33-2
3,5-dinitrobenoyl chloride

: 87417-20-7
3,5-Dinitro-benzoic acid (S)-3-[2-[(1R,3aS,7aR)-1-((R)-5-hydroxy-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-(4E)-ylidene]-eth-(E)-ylidene]-4-methylene-cyclohexyl ester

Guidance literature:: With pyridine;
DOI:10.1021/jo00375a013

Reference yield:

: 2579-08-0
ergocalciferol acetate

: 87417-20-7
3,5-Dinitro-benzoic acid (S)-3-[2-[(1R,3aS,7aR)-1-((R)-5-hydroxy-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-(4E)-ylidene]-eth-(E)-ylidene]-4-methylene-cyclohexyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 54 percent / lead tetraacetate, acetic acid / CH₂Cl₂ / 0 °C

2: 1.) O₃, 2.) triphenylphosphine / 1.) CH₂Cl₂, -78 deg C, 2.) CH₂Cl₂, -78 deg C, 30 min

3: 1.) phenyllithium / 1.) THF, 2.) benzene, THF, 3 min

4: 85 percent / aq. acetic acid / tetrahydrofuran / 15 h

5: H₂, NaHCO₃; / 5percent Pt/C / benzene; ethanol / 24 h

6: NaOH / benzene; methanol / 0.33 h / Ambient temperature

7: 1.) hydrazine, 2.) dianisyl telluroxide / 1.) ethanol, reflux, overnight, 2.) water, CH₂Cl₂, 1,2-dibromotetrachloroethane, 5 h

8: 70 percent / pyridine

With pyridine; lead(IV) acetate; sodium hydroxide; di-(p-methoxyphenyl)tellurium oxide; hydrogen; sodium hydrogencarbonate; ozone; acetic acid; phenyllithium; triphenylphosphine; hydrazine; platinum on activated charcoal; In tetrahydrofuran; methanol; ethanol; dichloromethane; benzene;
DOI:10.1021/jo00375a013

Reference yield:

: 104973-29-7
6(S),19-(N,N'-phthalhydrazido)-3β-acetoxy-20(S)-formyl-9,10-secopregna-5(10),7(E)-diene

: 87417-20-7
3,5-Dinitro-benzoic acid (S)-3-[2-[(1R,3aS,7aR)-1-((R)-5-hydroxy-1,5-dimethyl-hexyl)-7a-methyl-octahydro-inden-(4E)-ylidene]-eth-(E)-ylidene]-4-methylene-cyclohexyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) phenyllithium / 1.) THF, 2.) benzene, THF, 3 min

2: 85 percent / aq. acetic acid / tetrahydrofuran / 15 h

3: H₂, NaHCO₃; / 5percent Pt/C / benzene; ethanol / 24 h

4: NaOH / benzene; methanol / 0.33 h / Ambient temperature

5: 1.) hydrazine, 2.) dianisyl telluroxide / 1.) ethanol, reflux, overnight, 2.) water, CH₂Cl₂, 1,2-dibromotetrachloroethane, 5 h

6: 70 percent / pyridine

With pyridine; sodium hydroxide; di-(p-methoxyphenyl)tellurium oxide; hydrogen; sodium hydrogencarbonate; acetic acid; phenyllithium; hydrazine; platinum on activated charcoal; In tetrahydrofuran; methanol; ethanol; benzene;
DOI:10.1021/jo00375a013