Technology Process of cis-Mo(CO)4((NC5H4)[(Ph2PNH)C(NSiMe3)]-4)
There total 1 articles about cis-Mo(CO)4((NC5H4)[(Ph2PNH)C(NSiMe3)]-4) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
tetrahydrofuran;
under dry N2; the Mo complex and ligand were mixed at 0°C, soln. was warmed to room temp. slowly and stirred for 1 d; soln. was filtered, pumped to dryness, residue was washed with Et2O-hexane, redissolved in CH2Cl2, filtered, soln. was stored for 2 d at room temp., ppt. was filtered off, dried in vac.; elem. anal.;
DOI:10.1016/S0022-328X(00)00475-7
- Guidance literature:
-
In
tetrahydrofuran;
under dry N2; the soln. was stirred at ambient temp. for 1 d; soln. was filtered, pumped to dryness, residue was washed with Et2O, dissolved in CH2Cl2 and filtered, hexane was added, mixt. was stored for 3 d, filtered, filtrate was cooled at -5°C for 2 d, ppt. was filtered off, dried in vac.; elem. anal.;
DOI:10.1016/S0022-328X(00)00475-7
![(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum<sup>(0)</sup>](/Databaselist/images/loading.webp)
