Technology Process of C5(3,5-C6H3Me2)4(3,5-C6H3F2)Br
There total 7 articles about C5(3,5-C6H3Me2)4(3,5-C6H3F2)Br which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
pyridine; dibromo sulfoxide;
In
dichloromethane;
at -10 - 20 ℃;
Title compound not separated from byproducts;
DOI:10.1016/S0022-328X(01)00725-2
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: 87 percent / Br2 / 140 °C
2.1: HCHO; HMTA / H2O
3.1: KCN / H2O
4.1: NH4NO3
5.1: 75 percent / benzyltrimethylammonium hydroxide / ethanol / 0.25 h / Heating
6.1: toluene; tetrahydrofuran / -80 °C
6.2: 40 percent / aq. NH4Cl / 20 °C
7.1: SOBr2; pyridine / CH2Cl2 / -10 - 20 °C
With
pyridine; ammonium nitrate; potassium cyanide; sulfurous dibromide; formaldehyd; hexamethylenetetramine; bromine; N-benzyl-trimethylammonium hydroxide;
In
tetrahydrofuran; ethanol; dichloromethane; water; toluene;
1.1: Kadesh-Shacklett reaction;
DOI:10.1016/S0022-328X(01)00725-2
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: KCN / H2O
2.1: NH4NO3
3.1: 75 percent / benzyltrimethylammonium hydroxide / ethanol / 0.25 h / Heating
4.1: toluene; tetrahydrofuran / -80 °C
4.2: 40 percent / aq. NH4Cl / 20 °C
5.1: SOBr2; pyridine / CH2Cl2 / -10 - 20 °C
With
pyridine; ammonium nitrate; potassium cyanide; sulfurous dibromide; N-benzyl-trimethylammonium hydroxide;
In
tetrahydrofuran; ethanol; dichloromethane; water; toluene;
DOI:10.1016/S0022-328X(01)00725-2
