[Ni(II)(xanthate)(tetraphenyldiphosphinoethane)]

Base Information

• Chemical Name: [Ni(II)(xanthate)(tetraphenyldiphosphinoethane)]
• CAS No.: 107568-47-8
• Molecular Formula: C₂₇H₂₄NiOP₂S₂
• Molecular Weight: 549.256
• Mol file: 107568-47-8.mol

Synonyms:

Chemical Property of [Ni(II)(xanthate)(tetraphenyldiphosphinoethane)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ni(II)(xanthate)(tetraphenyldiphosphinoethane)]

There total 2 articles about [Ni(II)(xanthate)(tetraphenyldiphosphinoethane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(methylxanthato)nickel(II) (3427-49-4) → [Ni(II)(xanthate)(tetraphenyldiphosphinoethane)] (107568-47-8)

Guidance literature:

With 1,2-bis(diphenylphosphino)ethane; In chloroform; acetone; Ni(S2COMe) and dppe in acetone-chloroform (2:1) were stirred for 24 h; the solvent was removed to one-fifth of the vol. at reduced pressure and the solid formed was recrystd. from acetone; elem. anal.;

DOI:10.1039/DT9870000281

Reference yield:

1,2-bis-(diphenylphosphino)ethane (1663-45-2) + dithiocarbonic acid O-isopropyl ester; nickel (II)-compound → [Ni(II)(xanthate)(tetraphenyldiphosphinoethane)] (107568-47-8)

Guidance literature:

In butanone; soln. of Ni-complex treated with soln. of dppe, molar ratio Ni-salt:dppe=1:1; slow evapd., filtered, washed (butan-2-one), dried in vacuo; elem. anal.;

DOI:10.1016/S0277-5387(03)00399-1

Reference yield:

[Ni(II)(xanthate)(tetraphenyldiphosphinoethane)] (107568-47-8) → {NiJ2-1.2-Bis-diphenylphosphino-aethan} (15629-91-1,47671-01-2)

Guidance literature:

With CH₃I; In chloroform; addn. of an excess of CH3I to a soln. of Ni(S2CO)(dppe) in CHCl3 under N2; refluxing for 10 min;; evapn. to dryness; addn. of acetone; ppt. was filtered off, washed with acetone, and dried under vac.;;

DOI:10.1039/DT9870000281

upstream raw materials:

1,2-bis-(diphenylphosphino)ethane

bis(methylxanthato)nickel(II)

Downstream raw materials:

{NiJ₂-1.2-Bis-diphenylphosphino-aethan}

dibromo[1,2-bis(diphenylphosphino)ethane]nickel(II)