1D-(1,2,5/3,4)-1,2,3,4-tetra-O-benzoyl-5-C-methyl-1,2,3,4-cyclohexanetetrol

Base Information

Chemical Name:1D-(1,2,5/3,4)-1,2,3,4-tetra-O-benzoyl-5-C-methyl-1,2,3,4-cyclohexanetetrol
CAS No.:110892-05-2
Molecular Formula:C₃₅H₃₀O₈
Molecular Weight:578.618
Hs Code.:

Synonyms:

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Chemical Property of 1D-(1,2,5/3,4)-1,2,3,4-tetra-O-benzoyl-5-C-methyl-1,2,3,4-cyclohexanetetrol

Chemical Property:

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Technology Process of 1D-(1,2,5/3,4)-1,2,3,4-tetra-O-benzoyl-5-C-methyl-1,2,3,4-cyclohexanetetrol

There total 54 articles about 1D-(1,2,5/3,4)-1,2,3,4-tetra-O-benzoyl-5-C-methyl-1,2,3,4-cyclohexanetetrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 113831-72-4
6,7-Didesoxy-2,3;4,5-di-O-isopropyliden-L-gluco-hept-6-enose-trimethylendithioacetal

: 110892-05-2,141436-40-0,141436-41-1,141436-42-2,141436-43-3,141436-44-4,141436-46-6,141436-47-7
C₃₅H₃₀O₈

Guidance literature:: Multi-step reaction with 7 steps

1: 2,4,6-collidine, CH₃I / acetone; H₂O / Heating

2: NaBH₄ / aq. ethanol

3: 83 percent / imidazole, PPh₃, I₂ / toluene

4: aq. acetic acid / trifluoroacetic acid / Ambient temperature; overnight

5: pyridine / Ambient temperature

6: tributyltin hydride, azobisisobutyronitrile (AIBN) / acetone / 2 h / Heating

7: 1.) aq. acetic acid; 2.) pyridine

With pyridine; 1H-imidazole; 2,4,6-trimethyl-pyridine; sodium tetrahydroborate; 2,2'-azobis(isobutyronitrile); iodine; tri-n-butyl-tin hydride; acetic acid; triphenylphosphine; methyl iodide; trifluoroacetic acid; In ethanol; water; acetone; toluene;
DOI:10.1016/0008-6215(92)84055-W

Reference yield:

: 113831-72-4
6,7-Didesoxy-2,3;4,5-di-O-isopropyliden-L-gluco-hept-6-enose-trimethylendithioacetal

: 110892-05-2,141436-40-0,141436-41-1,141436-42-2,141436-43-3,141436-44-4,141436-46-6,141436-47-7
C₃₅H₃₀O₈

Guidance literature:: Multi-step reaction with 7 steps

1: 2,4,6-collidine, CH₃I / acetone; H₂O / Heating

2: NaBH₄ / aq. ethanol

3: 83 percent / imidazole, PPh₃, I₂ / toluene

4: aq. acetic acid / trifluoroacetic acid / Ambient temperature; overnight

5: pyridine / Ambient temperature

6: tributyltin hydride, azobisisobutyronitrile (AIBN) / acetone / 2 h / Heating

7: 1.) aq. acetic acid; 2.) pyridine

With pyridine; 1H-imidazole; 2,4,6-trimethyl-pyridine; sodium tetrahydroborate; 2,2'-azobis(isobutyronitrile); iodine; tri-n-butyl-tin hydride; acetic acid; triphenylphosphine; methyl iodide; trifluoroacetic acid; In ethanol; water; acetone; toluene;
DOI:10.1016/0008-6215(92)84055-W

Reference yield:

: 141410-43-7
benzyl 6-O-(tert-butyldiphenylsilyl)-β-D-galactopyranoside

: 110892-05-2,141436-40-0,141436-41-1,141436-42-2,141436-43-3,141436-44-4,141436-46-6,141436-47-7
1-L-(1,3,4/2,5)-2,3,4,5-tetra-O-benzoyl-1-C-methyl-2,3,4,5-cyclohexanetetrol

Guidance literature:: Multi-step reaction with 10 steps

1: 78 percent / CaSO₄ / p-toluenesulfonic acid / 15 h / Ambient temperature

2: 93 percent / hydrogen / 10percent Pd/C, NaHCO₃ / methanol / 24 h / 760 Torr

3: 1.) BuLi / 1.) THF, hexane, -5 deg C, 1 h; 2.) THF, r.t., 36 h

4: 91 percent / Bu₄NF / tetrahydrofuran

5: pyridine / CH₂Cl₂

6: pyridine / CH₂Cl₂ / 1 h

7: 81 percent / NaI / tetrahydrofuran

8: tributyltin hydride, azobisisobutyronitrile (AIBN) / benzene / 2 h / Heating

9: NaOCH₃ / methanol

10: 1.) aq. acetic acid; 2.) pyridine

With pyridine; calcium sulfate; n-butyllithium; 2,2'-azobis(isobutyronitrile); tetrabutyl ammonium fluoride; hydrogen; tri-n-butyl-tin hydride; sodium methylate; acetic acid; sodium iodide; palladium on activated charcoal; sodium hydrogencarbonate; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; dichloromethane; benzene;
DOI:10.1016/0008-6215(92)84055-W