grayanotoxin III

Base Information

• Chemical Name: grayanotoxin III
• CAS No.: 39864-85-2
• Molecular Formula: C₂₀H₃₄O₆
• Molecular Weight: 370.486
• Mol file: 39864-85-2.mol

Synonyms:

Chemical Property of grayanotoxin III

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of grayanotoxin III

There total 3 articles about grayanotoxin III which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(3aR)-2c,4t,8t,11c,11ac-Pentahydroxy-12anti-acetoxy-1,1,4c,8-tetramethyl-(3arH,4acH)-tetradecahydro-7t,9at-methano-cyclopenta[b]heptalen (4619-00-5,4720-09-6) → (3aR)-2c,4t,8t,11c,11ac,12anti-Hexahydroxy-1,1,4c,8c-tetramethyl-(3arH,4acH)-tetradecahydro-7t,9at-methano-cyclopenta[b]heptalen (4678-45-9,6855-95-4,25530-65-8,30460-38-9,39864-85-2)

Guidance literature:

With sodium hydroxide;

DOI:10.1021/ja01573a080

Reference yield:

Pieristoxin I (84893-93-6) → grayanotoxin III (4678-45-9,6855-95-4,25530-65-8,30460-38-9,39864-85-2)

Guidance literature:

With IRA 400 (OH form); In methanol;

Reference yield:

→ 10-Epi-grayanotoxin III (4678-45-9,6855-95-4,25530-65-8,30460-38-9,39864-85-2)

Guidance literature:

Grayanotoxin II-Epoxid, LiAlH4;

DOI:10.1016/0040-4020(72)88142-0

upstream raw materials:

(3aR)-2c,4t,8t,11c,11ac-Pentahydroxy-12anti-acetoxy-1,1,4c,8-tetramethyl-(3arH,4acH)-tetradecahydro-7t,9at-methano-cyclopenta[b]heptalen

Pieristoxin I

Downstream raw materials:

Grayanotoxin-II

Refernces

• 1、 Katai, Masaaki,Fujiwara, Masayoshi,Terai, Tadamasa,Meguri, Haruo. "Studies on the Constituents of the Leaves of Pieris japonica D. Don". . p. 3124 - 3126. Retrieved 2007/10/02.